Metal-Free Photoinduced Electron Transfer–Atom Transfer Radical Polymerization Integrated with Bioinspired Polydopamine Chemistry as a Green Strategy for Surface Engineering of Magnetic Nanoparticles

2017 ◽  
Vol 9 (15) ◽  
pp. 13637-13646 ◽  
Author(s):  
Yang Yang ◽  
Xuegang Liu ◽  
Gang Ye ◽  
Shan Zhu ◽  
Zhe Wang ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Magnetic Nanoparticles ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Photoinduced Electron Transfer ◽  
Surface Engineering ◽  
Atom Transfer ◽  
Metal Free ◽  
Green Strategy

Metal-free photoinduced electron transfer–atom transfer radical polymerization (PET–ATRP) via a visible light organic photocatalyst

2016 ◽  
Vol 7 (3) ◽  
pp. 689-700 ◽  
Author(s):  
Xiaodong Liu ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
Xiulin Zhu
Keyword(s):  
Electron Transfer ◽  
Visible Light ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Photoinduced Electron Transfer ◽  
Atom Transfer ◽  
Metal Free ◽  
Polymer Architectures ◽  
Reductive Pathway

This work developed the first example of PET-ATRP using a reductive pathway, which provides new opportunities for the synthesis of well-controlled polymer architectures through a photochemical approach.

scholarly journals A Cu(ii) metal–organic framework as a recyclable catalyst for ARGET ATRP

2016 ◽  
Vol 7 (47) ◽  
pp. 7199-7203 ◽  
Author(s):  
Hui-Chun Lee ◽  
Markus Antonietti ◽  
Bernhard V. K. J. Schmidt
Keyword(s):  
Electron Transfer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Metal Organic Framework ◽  
Recyclable Catalyst ◽  
Atom Transfer ◽  
Arget Atrp ◽  
Metal Organic ◽  
Organic Framework

A Cu(ii) MOF can serve as an comprehensive catalyst for activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP) in the synthesis of benzyl methacrylate, styrene, isoprene and 4-vinylpyridine.

Photoinduced Metal-Free Atom Transfer Radical Polymerization of Acrylonitrile

2015 ◽  
Vol 4 (2) ◽  
pp. 192-196 ◽  
Author(s):  
Xiangcheng Pan ◽  
Melissa Lamson ◽  
Jiajun Yan ◽  
Krzysztof Matyjaszewski
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Free Atom ◽  
Atom Transfer ◽  
Metal Free

Controlled synthesis of poly[(butyl methacrylate)-co -(butyl acrylate)] via activator regenerated by electron transfer atom transfer radical polymerization: insights and improvement

2014 ◽  
Vol 63 (5) ◽  
pp. 848-857 ◽  
Author(s):  
Kevin A Payne ◽  
Paul HM Van Steenberge ◽  
Dagmar R D'hooge ◽  
Marie-Françoise Reyniers ◽  
Guy B Marin ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Butyl Acrylate ◽  
Butyl Methacrylate ◽  
Controlled Synthesis ◽  
Atom Transfer

scholarly journals Advances in Organocatalyzed Atom Transfer Radical Polymerization

2019 ◽  
Vol 2019 ◽  
pp. 1-9 ◽  
Author(s):  
Xin Hu ◽  
Ning Zhu ◽  
Kai Guo
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Feasible Solution ◽  
Metal Catalyst ◽  
Catalyst Loading ◽  
Limiting Factor ◽  
Atom Transfer ◽  
Significant Progress ◽  
Future Directions ◽  
Metal Free

Atom transfer radical polymerization (ATRP) is one of the most robust tools to prepare well-defined polymers with precise topologies and architectures. Although series of improved ATRP methods have been developed to decrease the metal catalyst loading to parts per million, metal residue is the key limiting factor for variety of applications, especially in microelectronic and biomedical area. The feasible solution to this challenge would be the establishment of metal-free ATRP. Since 2014, organocatalyzed ATRP (O-ATRP) or metal free ATRP has achieved significant progress by developing kinds of organic photoredox catalysts. This review highlights the advances in organocatalyzed atom transfer radical polymerization as well as the potential future directions.

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