Chromium(II) Metal–Organic Polyhedra as Highly Porous Materials

2017 ◽  
Vol 9 (33) ◽  
pp. 28064-28068 ◽  
Author(s):  
Jinhee Park ◽  
Zachary Perry ◽  
Ying-Pin Chen ◽  
Jaeyeon Bae ◽  
Hong-Cai Zhou
Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3512
Author(s):  
Reem Shomal ◽  
Babatunde Ogubadejo ◽  
Toyin Shittu ◽  
Eyas Mahmoud ◽  
Wei Du ◽  
...  

Biodiesel is a promising candidate for sustainable and renewable energy and extensive research is being conducted worldwide to optimize its production process. The employed catalyst is an important parameter in biodiesel production. Metal–organic frameworks (MOFs), which are a set of highly porous materials comprising coordinated bonds between metals and organic ligands, have recently been proposed as catalysts. MOFs exhibit high tunability, possess high crystallinity and surface area, and their order can vary from the atomic to the microscale level. However, their catalytic sites are confined inside their porous structure, limiting their accessibility for biodiesel production. Modification of MOF structure by immobilizing enzymes or ionic liquids (ILs) could be a solution to this challenge and can lead to better performance and provide catalytic systems with higher activities. This review compiles the recent advances in catalytic transesterification for biodiesel production using enzymes or ILs. The available literature clearly indicates that MOFs are the most suitable immobilization supports, leading to higher biodiesel production without affecting the catalytic activity while increasing the catalyst stability and reusability in several cycles.


2012 ◽  
Vol 69 ◽  
pp. 115-126 ◽  
Author(s):  
Martin Salzer ◽  
Aaron Spettl ◽  
Ole Stenzel ◽  
Jan-Henrik Smått ◽  
Mika Lindén ◽  
...  

2020 ◽  
Author(s):  
Tatsuaki Okada ◽  
Satoshi Tanaka ◽  
Yuri Shimaki ◽  
Naoya Sakatani ◽  
Takehiko Arai ◽  
...  

<p>Thermal imaging, or thermography, has revealed the surface physical state of the C-type near-Earth asteroid 162173 Ryugu (Okada et al., 2020). The asteroid is the target body of JAXA Hayabsua2 asteroid sample return mission, and it has been characterized through remote sensing and surface experiments, and will be deeply and accurately investigated by analysis of returned sample. Thermal observations are among such multi-scale observations, providing a new insight into understanding planetary evolution process.</p> <p>Thermal infrared imager TIR (Okada et al., 2017; 2020) was used to take one-rotation global thermal images of Ryugu at every 6° step, from the home position (20 km altitude) or from the Mid-Altitude (5 km altitude). There were two big surprises contrary to the predictions before arrival at Ryugu: i) flat diurnal temperature profiles compared to the case of non-rough surface, and ii) non-cold spots identified for most of boulders. The flat diurnal temperature profiles and its maximum temperature in a day indicate that Ryugu must have very rough surfaces made of highly porous materials, derived from the thermal inertia of 300 ± 100 J K<sup>-1</sup>s<sup>-0.5</sup>m<sup>-2</sup> (hereafter, tiu). Non-cold boulders indicate that boulders are less consolidated or compacted than typical carbonaceous chondrite meteorites, and shows the same thermophysical properties as the surroundings. TIR was also used to take close-up thermal images during the descent operations, and to have proven that the surface of asteroid is covered with fragments of porous rocks, larger than several centimeters in diameter. The typical size of fragments larger than thermal skin depth (~35 mm) results in similar thermal properties between the boulders and their surroundings. We also consider the surface roughness effect (Shimaki et al., 2020) to obtain the maps of thermal inertia ( 225 ± 45 tiu) and the roughness (0.41 ± 0.05) at the same time, corresponding to very rough surfaces made of highly-porous materials. This thermal inertia is basically consistent with the value (282 +93/-35 tiu) by in situ measurement using a thermal radiometer MARA on MASCOT lander (Grott et al., 2019). Furthermore, in the close-up thermal images, there were found boulders colder by 20 °C or more, indicating the thermal inertia of typical carbonaceous chondrite meteorites.</p> <p>Considering these results, we proposed a formation scenario of Ryugu: fluffy cosmic dusts gathered to form porous planetesimals, and then much larger sized but still porous bodies. A low degree of consolidation and alteration has occurred at most of the body, while a higher degree of consolidation or alteration proceeded at the deep interior. Huge meteoritic impacts destroyed and fragmented the bodies, and part of those fragments were re-accreted to form the next generation, rubble-pile bodies (asteroids). Boulders found on Ryugu might have originated from the deep interior of parent bodies, so that most of them are very porous and less consolidated but some of them are relatively dense materials similar to carbonaceous chondrites, which might have originated from the interior. Due to YORP effect, the rotation rate decreased to current one, and the current shape of a spinning top-shape were formed. Analysis of returned sample will make progress in our knowledge of the planetary formation process.</p>


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