Nanoporous Adsorption Effect on Alteration of the Li+ Diffusion Pathway by a Highly Ordered Porous Electrolyte Additive for High-Rate All-Solid-State Lithium Metal Batteries

2018 ◽  
Vol 10 (28) ◽  
pp. 23874-23882 ◽  
Author(s):  
Wenwen Li ◽  
Sanpei Zhang ◽  
Bangrun Wang ◽  
Sui Gu ◽  
Dong Xu ◽  
...  
Keyword(s):  
Solid State ◽  
High Rate ◽  
Lithium Metal ◽  
Electrolyte Additive ◽  
Adsorption Effect ◽  
Diffusion Pathway ◽  
Lithium Metal Batteries ◽  
Ordered Porous

High Rate and Stable Solid-State Lithium Metal Batteries Enabled by Electronic and Ionic Mixed Conducting Network Interlayers

2019 ◽  
Vol 11 (18) ◽  
pp. 16578-16585 ◽  
Author(s):  
Zhengxin Zhu ◽  
Lei-Lei Lu ◽  
Yichen Yin ◽  
Jiaxin Shao ◽  
Bao Shen ◽  
...  
Keyword(s):  
Solid State ◽  
High Rate ◽  
Lithium Metal ◽  
Lithium Metal Batteries

scholarly journals An Electron/Ion Dual‐Conductive Alloy Framework for High‐Rate and High‐Capacity Solid‐State Lithium‐Metal Batteries

2018 ◽  
Vol 31 (3) ◽  
pp. 1804815 ◽  
Author(s):  
Chunpeng Yang ◽  
Hua Xie ◽  
Weiwei Ping ◽  
Kun Fu ◽  
Boyang Liu ◽  
...  
Keyword(s):  
Solid State ◽  
High Capacity ◽  
High Rate ◽  
Lithium Metal ◽  
Lithium Metal Batteries

scholarly journals Tuning of Composition and Morphology of LiFePO4 Cathode for Applications in All Solid-State Lithium Metal Batteries

2022 ◽  
Author(s):  
Erabhoina Harimohan ◽  
Mukundan Thelakkat
Keyword(s):  
Solid State ◽  
Active Material ◽  
High Rate ◽  
Solid Polymer ◽  
Lithium Metal ◽  
Electron Conduction ◽  
Transport Pathways ◽  
Lithium Metal Batteries ◽  
Ion Conducting ◽  
Discharge Capacities

Abstract All solid-state rechargeable lithium metal batteries (SS-LMBs) are gaining more and more importance because of their higher safety and higher energy densities in comparison to their liquid-based counterparts. In spite of this potential, their low discharge capacities and poor rate performances limit them to be used as state-of-the-art SS-LMBs. This arise due to the low intrinsic ionic and electronic transport pathways within the solid components in the cathode during the fast charge/discharge processes. Therefore, it is necessary to have a cathode with good electron conducting channels to increase the active material utilization without blocking the movement of lithium ions. Since SS-LMBs require a different morphology and composition of the cathode, we selected LiFePO4 (LFP) as a prototype and, we have systematically studied the influence of the cathode composition by varying the contents of active material LFP, conductive additives (super C65 conductive carbon black and conductive graphite), ion conducting components (PEO and LiTFSI) in order to elucidate the best ion as well as electron conduction morphology in the cathode. In addition, a comparative study on different cathode slurry preparation methods was made, wherein ball milling was found to reduce the particle size and increase the homogeneity of LFP which further aids fast Li ion transport throughout the electrode. The SEM analysis of the resulting calendered electrode shows the formation of non-porous and crack-free structures with the presence of conductive graphite throughout the electrode. As a result, the optimum LFP cathode composition with solid polymer nanocomposite electrolyte (SPNE) delivered higher initial discharge capacities of 114 mAh g-1 at 0.2C rate at 30 ᴼC and 141 mAh g-1 at 1C rate at 70 ᴼC. When the current rate was increased to 2C, the electrode still delivered high discharge capacity of 82 mAh g-1 even after 500 cycle, which indicates that the optimum cathode formulation is one of the important parameters in building high rate and long cycle performing SS-LMBs.

3D Fiber Skeleton Reinforced PEO -Based Polymer Electrolyte for High Rate and Ultra-Long Cycle All-Solid-State Battery

2021 ◽  
Author(s):  
zhangqin shi ◽  
Wenyao Guo ◽  
luozeng zhou ◽  
Qunjie Xu ◽  
Yulin Min
Keyword(s):  
Mechanical Properties ◽  
Solid State ◽  
Polyethylene Oxide ◽  
Polymer Electrolytes ◽  
Solid Electrolytes ◽  
Room Temperature ◽  
High Rate ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Solid State Battery

Polyethylene oxide (PEO)-based polymer electrolytes are potential replacements for safer solid electrolytes in next-generation lithium metal batteries. However, the lower room temperature ionic conductivity and poor mechanical properties greatly hinder...

A painted layer for high-rate and high-capacity solid-state lithium–metal batteries

2019 ◽  
Vol 55 (47) ◽  
pp. 6704-6707 ◽  
Author(s):  
Bin Sun ◽  
Yang Jin ◽  
Jialiang Lang ◽  
Kai Liu ◽  
Minghao Fang ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
High Capacity ◽  
High Rate ◽  
Lithium Metal ◽  
Alloy Anode ◽  
Lithium Metal Batteries ◽  
Spraying Method ◽  
Painted Layer

Based on a garnet solid electrolyte, an electron/ion dual-conductive framework established by a spraying method enabled an alloy anode that realized a high-rate operation.

Garnet-rich composite solid electrolytes for dendrite-free, high-rate, solid-state lithium-metal batteries

2020 ◽  
Vol 26 ◽  
pp. 448-456 ◽  
Author(s):  
Chaoyi Yan ◽  
Pei Zhu ◽  
Hao Jia ◽  
Zhuang Du ◽  
Jiadeng Zhu ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
High Rate ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Composite Solid Electrolytes ◽  
Composite Solid

Flame-retardant single-ion conducting polymer electrolytes based on anion acceptors for high-safety lithium metal batteries

2021 ◽  
Author(s):  
Kuirong Deng ◽  
Tianyu Guan ◽  
Fuhui Liang ◽  
Xiaoqiong Zheng ◽  
Qingguang Zeng ◽  
...  
Keyword(s):  
Solid State ◽  
Flame Retardant ◽  
Conducting Polymer ◽  
Polymer Electrolytes ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anodes ◽  
Ion Conducting ◽  
Ion Conducting Polymer ◽  
Metal Anodes

Solid-state lithium metal batteries (LMBs) assembled with polymer electrolytes (PEs) and lithium metal anodes are promising batteries owing to their enhanced safeties and ultrahigh theoretical energy densities. Nevertheless, polymer electrolytes...

Double-Layered Multifunctional Composite Electrolytes for High-Voltage Solid-State Lithium-Metal Batteries

2021 ◽  
Vol 13 (10) ◽  
pp. 11958-11967
Author(s):  
Zhongran Yao ◽  
Kongjun Zhu ◽  
Xia Li ◽  
Jie Zhang ◽  
Jun Li ◽  
...  
Keyword(s):  
Solid State ◽  
High Voltage ◽  
Lithium Metal ◽  
Composite Electrolytes ◽  
Lithium Metal Batteries
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