Stereogenic-at-Iron Catalysts with a Chiral Tripodal Pentadentate Ligand

ACS Catalysis ◽  
2021 ◽  
pp. 7467-7476
Author(s):  
Philipp S. Steinlandt ◽  
Xiulan Xie ◽  
Sergei Ivlev ◽  
Eric Meggers
Keyword(s):  
Iron Catalysts ◽  
Pentadentate Ligand

A NGR STUDY OF IRON CATALYSTS IN CO HYDROCONDENSATION REACTIONS

1980 ◽  
Vol 41 (C1) ◽  
pp. C1-339-C1-340
Author(s):  
N. Nahon ◽  
V. Perrichon ◽  
P. Turlier ◽  
P. Bussière
Keyword(s):  
Iron Catalysts

Oxygen-Oxygen Bond Cleavage and Formation in Co(II) Mediated Stoichiometric O2 Reduction via the Potential Intermediacy of a Co(IV) Oxyl Radical

2018 ◽  
Author(s):  
Lucie Nurdin ◽  
Denis M. Spasyuk ◽  
Laura Fairburn ◽  
Warren Piers ◽  
Laurent Maron
Keyword(s):  
Bond Cleavage ◽  
Peroxo Complex ◽  
Oxygen Oxygen ◽  
O2 Reduction ◽  
Oxygen Bond ◽  
Pentadentate Ligand

Diprotonation of a remarkably stable, toluene soluble cobalt peroxo complex supported by a neutral, dianionic pentadentate ligand leads to facile O-O bond cleavage and production of a highly reactive Co(IV) oxyl cation intermediate that dimerizes and releases O<sub>2</sub>. These processes are relevant to both O<sub>2</sub> reduction and O<sub>2</sub> evolution and the mechanism was probed in detail both experimentally and computationally.

scholarly journals Activation of ammonia and hydrazine by electron rich Fe(ii) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe(iii) amido intermediate

2021 ◽  
Author(s):  
Lucie Nurdin ◽  
Yan Yang ◽  
Peter G. N. Neate ◽  
Warren E. Piers ◽  
Laurent Maron ◽  
...  
Keyword(s):  
Transition Metal ◽  
Ammonia Oxidation ◽  
Oxidation Processes ◽  
Pentadentate Ligand

Synopsis: a highly reactive Fe(iii)–NH2 complex is generated via activation of ammonia or hydrazine in reactions of relevance to fundamental steps in ammonia oxidation processes mediated by an abundant, first row transition metal.

scholarly journals Cover Feature: Precursor Nuclearity and Ligand Effects in Atomically‐Dispersed Heterogeneous Iron Catalysts for Alkyne Semi‐Hydrogenation (ChemCatChem 14/2021)

ChemCatChem ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 3199-3199
Author(s):  
Dario Faust Akl ◽  
Andrea Ruiz‐Ferrando ◽  
Edvin Fako ◽  
Roland Hauert ◽  
Olga Safonova ◽  
...  
Keyword(s):  
Iron Catalysts ◽  
Ligand Effects

Development of New Iron Catalysts for the Tandem Isomerization—Aldol Condensation of Allylic Alcohols.

ChemInform ◽  
2003 ◽  
Vol 34 (49) ◽  
Author(s):  
Ramalinga Uma ◽  
Nicolas Gouault ◽  
Christophe Crevisy ◽  
Rene Gree
Keyword(s):  
Aldol Condensation ◽  
Iron Catalysts ◽  
Allylic Alcohols

Polymerization of Methyl Methacrylate Using Four-Coordinate (α-Diimine)iron Catalysts:  Atom Transfer Radical Polymerization vs Catalytic Chain Transfer

2003 ◽  
Vol 36 (8) ◽  
pp. 2591-2593 ◽  
Author(s):  
Vernon C. Gibson ◽  
Rachel K. O'Reilly ◽  
Duncan F. Wass ◽  
Andrew J. P. White ◽  
David J. Williams
Keyword(s):  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Chain Transfer ◽  
Iron Catalysts ◽  
Atom Transfer ◽  
Catalytic Chain Transfer

Studies of the Fischer—Tropsch Synthesis. IX. Phase Changes of Iron Catalysts in the Synthesis

1951 ◽  
Vol 73 (3) ◽  
pp. 944-946 ◽  
Author(s):  
Robert B. Anderson ◽  
L. J. E. Hofer ◽  
Ernst M. Cohn ◽  
Bernard Seligman
Keyword(s):  
Tropsch Synthesis ◽  
Phase Changes ◽  
Iron Catalysts ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis

Microcalorimetric Studies of Surface Acid/Base Properties of Magnesium Iron Catalysts Prepared from Hydrotalcite-Type Precursors

1997 ◽  
Vol 128 (1) ◽  
pp. 73-79 ◽  
Author(s):  
Mai Tu ◽  
Jianyi Shen ◽  
Yi Chen
Keyword(s):  
Iron Catalysts ◽  
Acid Base ◽  
Base Properties
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