Synergistic Effect in Ir- or Pt-Doped Ru Nanoparticles: Catalytic Hydrogenation of Carbonyl Compounds under Ambient Temperature and H2 Pressure

Treatment of 2-Mercaptothiazoline, 2-Mercaptobenzimidazole, 2-Mercapto-1- methylimidazole with [M2(CO)10] (M = Re and Mn) at ambient temperature in presence of decarbonylating reagent Me3NO give the complexes [Mn2(?-?2-C3H4NS2)2(CO)6] (1), [Re2(?-?2-C3H4NS2)2(CO)6] (2), [Mn2(?-?2-C7H5SN2)2(CO)6] (3), [Re2(?-?2- C7H5SN2)2(CO)6] (4), [Re2(?-?2-C4H5N2S)2(CO)6] (5) and [Re2(?1-C4H5N2SH)(CO)9] (6) respectively. All the compounds have been characterized by IR, 1H NMR and mass spectral data. The heterocyclic ligands are expected to be coordinated to two or single metal atom through the nitrogen and sulfur atoms or via only sulfur atom.DOI: http://dx.doi.org/10.3329/jbcs.v25i1.11775 Journal of Bangladesh Chemical Society, Vol. 25(1), 62-70, 2012>

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Catalytic Hydrogenation of Acetic Acid to Acetaldehyde: Synergistic Effect of Bifunctional Co/Ce‐Fe Oxide Solid Solution Catalysts

Chinese Journal of Chemistry ◽

10.1002/cjoc.201900055 ◽

2019 ◽

Vol 37 (7) ◽

pp. 709-719 ◽

Cited By ~ 2

Author(s):

Naixu Li ◽

Qi Zhang ◽

Rehana Bibi ◽

Quanhao Shen ◽

Richard Ngulube ◽

...

Keyword(s):

Solid Solution ◽

Acetic Acid ◽

Synergistic Effect ◽

Catalytic Hydrogenation ◽

Fe Oxide ◽

Oxide Solid Solution

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Supported RuB amorphous alloy mediated 1 atm hydrogenation of carbonyl compounds under ambient temperature

Catalysis Communications ◽

10.1016/j.catcom.2007.05.012 ◽

2008 ◽

Vol 9 (1) ◽

pp. 27-34 ◽

Cited By ~ 8

Author(s):

Hong-Bing Ji ◽

Yue-Ying Huang ◽

Li-Xia Pei ◽

Xing-Dong Yao

Keyword(s):

Amorphous Alloy ◽

Ambient Temperature ◽

Carbonyl Compounds

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Extracting chemical information from initial partial charges and electronic properties of reactants to predict order of chemical reactivity: Heterogeneous catalytic hydrogenation of homologue R–CO–X carbonyl compounds

Computational and Theoretical Chemistry ◽

10.1016/j.comptc.2010.11.034 ◽

2011 ◽

Vol 975 (1-3) ◽

pp. 24-30 ◽

Cited By ~ 1

Author(s):

Sándor Kristyan ◽

Sándor Gőbölös

Keyword(s):

Electronic Properties ◽

Catalytic Hydrogenation ◽

Carbonyl Compounds ◽

Chemical Reactivity ◽

Chemical Information ◽

Heterogeneous Catalytic ◽

Partial Charges ◽

Heterogeneous Catalytic Hydrogenation

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Mild and Selective Catalytic Hydrogenation of the C=C Bond in α,β-Unsaturated Carbonyl Compounds Using Supported Palladium Nanoparticles

Chemistry - A European Journal ◽

10.1002/chem.201600878 ◽

2016 ◽

Vol 22 (21) ◽

pp. 7184-7189 ◽

Cited By ~ 27

Author(s):

Anuja Nagendiran ◽

Vlad Pascanu ◽

Antonio Bermejo Gómez ◽

Greco González Miera ◽

Cheuk-Wai Tai ◽

...

Keyword(s):

Catalytic Hydrogenation ◽

Carbonyl Compounds ◽

Palladium Nanoparticles ◽

Supported Palladium

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A Metal-free Catalytic Reduction of α,β-unsaturated Carbonyl Compounds with Phenyldimethylsilane

Journal of Chemical Research ◽

10.3184/030823405774309131 ◽

2005 ◽

Vol 2005 (7) ◽

pp. 469-470 ◽

Cited By ~ 2

Author(s):

Ruizhu Mu ◽

Zhengang Liu ◽

Zhongquan Liu ◽

Li Yang ◽

Longmin Wu ◽

...

Keyword(s):

Ambient Temperature ◽

Carbonyl Compounds ◽

Catalytic Reduction ◽

Selective Reduction ◽

Catalytic Amount ◽

Metal Free

Selective reduction of α,β-unsaturated carbonyl compounds to the corresponding saturated ones by phenyldimethyl silane was promoted by a catalytic amount of I2O5 at ambient temperature in CH2Cl2.

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A simple and efficient method for the synthesis of gem-diacetates from aldehydes and ketones catalysed by gallium triiodide

Journal of Chemical Research ◽

10.3184/030823405774663066 ◽

2005 ◽

Vol 2005 (10) ◽

pp. 659-660 ◽

Cited By ~ 3

Author(s):

Peipei Sun ◽

Zhixin Hu

Keyword(s):

Acetic Anhydride ◽

Ambient Temperature ◽

Efficient Method ◽

Carbonyl Compounds ◽

Aldehydes And Ketones

Aldehydes or ketones reacted with acetic anhydride in dichloromethane at ambient temperature to produce gem-diacetates in good to excellent yields in the presence of gallium triiodide, which was generated in situ from gallium and iodine. This catalyst was also useful for the deprotection of carbonyl compounds in the presence of water.

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