Ambient-Temperature Synthesis of Primary Amines via Reductive Amination of Carbonyl Compounds

ACS Catalysis ◽  
2020 ◽  
Vol 10 (14) ◽  
pp. 7763-7772 ◽  
Author(s):  
Chao Xie ◽  
Jinliang Song ◽  
Manli Hua ◽  
Yue Hu ◽  
Xin Huang ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Carbonyl Compounds ◽  
Reductive Amination ◽  
Primary Amines ◽  
Temperature Synthesis

scholarly journals General and selective synthesis of primary amines using Ni-based homogeneous catalysts

2020 ◽  
Vol 11 (17) ◽  
pp. 4332-4339 ◽  
Author(s):  
Kathiravan Murugesan ◽  
Zhihong Wei ◽  
Vishwas G. Chandrashekhar ◽  
Haijun Jiao ◽  
Matthias Beller ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Reductive Amination ◽  
Primary Amines ◽  
Homogeneous Catalyst ◽  
Selective Synthesis ◽  
Homogeneous Catalysts

A Ni-triphos based homogeneous catalyst enabled the synthesis of all kinds of primary amines by reductive amination of carbonyl compounds with ammonia and hydrogenation of nitroarenes.

Self-regulated catalysis for selective synthesis of primary amines from carbonyl compounds

2021 ◽  
Author(s):  
Mingxia Gao ◽  
Xiuquan Jia ◽  
Jiping Ma ◽  
Xiaomeng Fan ◽  
Jin Gao ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Reductive Amination ◽  
Primary Amines ◽  
Selective Synthesis ◽  
General Synthesis

Most current processes for the general synthesis of primary amines by reductive amination are performed with enormously excessive amounts of hazardous ammonia. It remains unclear how catalysts should be designed...

scholarly journals A high performance catalyst of shape-specific ruthenium nanoparticles for production of primary amines by reductive amination of carbonyl compounds

2018 ◽  
Vol 9 (27) ◽  
pp. 5949-5956 ◽  
Author(s):  
Debraj Chandra ◽  
Yasunori Inoue ◽  
Masato Sasase ◽  
Masaaki Kitano ◽  
Asim Bhaumik ◽  
...  
Keyword(s):  
Chemical Industry ◽  
Carbonyl Compounds ◽  
High Performance ◽  
Reductive Amination ◽  
Metal Catalysts ◽  
Primary Amines ◽  
Ruthenium Nanoparticles ◽  
Active Surfaces ◽  
Highly Active ◽  
The Creation

The creation of metal catalysts with highly active surfaces is pivotal to meeting the strong economic demand of the chemical industry.

scholarly journals Ambient-Temperature Synthesis of (E)-N-(3-(tert-Butyl)-1-methyl-1H-pyrazol-5-yl)-1-(pyridin-2-yl)methanimine

Molbank ◽  
10.3390/m1250 ◽  
2021 ◽  
Vol 2021 (3) ◽  
pp. M1250
Author(s):  
Diana Becerra ◽  
Justo Cobo ◽  
Juan-Carlos Castillo
Keyword(s):  
Mass Spectrometry ◽  
Nmr Spectroscopy ◽  
Ambient Temperature ◽  
Magnesium Sulfate ◽  
Elemental Analysis ◽  
Condensation Reaction ◽  
2D Nmr ◽  
2D Nmr Spectroscopy ◽  
Temperature Synthesis ◽  
Tert Butyl

We report the ambient-temperature synthesis of novel (E)-N-(3-(tert-butyl)-1-methyl-1H-pyrazol-5-yl)-1-(pyridin-2-yl)methanamine 3 in 81% yield by a condensation reaction between 3-(tert-butyl)-1-methyl-1H-pyrazol-5-amine 1 and 2-pyridinecarboxaldehyde 2 in methanol using magnesium sulfate as a drying agent. The N-pyrazolyl imine 3 was full characterized by IR, 1D, and 2D NMR spectroscopy, mass spectrometry, and elemental analysis.

Microfluidic-enabled ambient-temperature synthesis of ultrasmall bimetallic nanoparticles

Nano Research ◽  
2021 ◽  
Author(s):  
Huayi Shi ◽  
Bin Song ◽  
Runzhi Chen ◽  
Qiang Zhang ◽  
Guyue Hu ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Bimetallic Nanoparticles ◽  
Temperature Synthesis

One-Pot Reductive Amination of Carbonyl Compounds Using Sodium Borohydride–Amberlyst 15

2010 ◽  
Vol 40 (7) ◽  
pp. 951-956 ◽  
Author(s):  
Heshmatollah Alinezhad ◽  
Mahmood Tajbakhsh ◽  
Nastaran Mahdavi
Keyword(s):  
Sodium Borohydride ◽  
Carbonyl Compounds ◽  
Reductive Amination ◽  
One Pot ◽  
Amberlyst 15
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