Engineering Ni3+ Cations in NiO Lattice at the Atomic Level by Li+ Doping: The Roles of Ni3+ and Oxygen Species for CO Oxidation

ACS Catalysis ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 8033-8045 ◽  
Author(s):  
Xianglan Xu ◽  
Lin Li ◽  
Jin Huang ◽  
Hua Jin ◽  
Xiuzhong Fang ◽  
...  
2020 ◽  
Vol 10 (20) ◽  
pp. 7067-7067
Author(s):  
Ningqiang Zhang ◽  
Lingcong Li ◽  
Rui Wu ◽  
Liyun Song ◽  
Lirong Zheng ◽  
...  

Correction for ‘Activity enhancement of Pt/MnOx catalyst by novel β-MnO2 for low-temperature CO oxidation: study of the CO–O2 competitive adsorption and active oxygen species’ by Ningqiang Zhang et al., Catal. Sci. Technol., 2019, 9, 347–354, DOI: 10.1039/C8CY01879K.


2001 ◽  
Vol 66 (11-12) ◽  
pp. 887-898 ◽  
Author(s):  
S.R. Brankovic ◽  
J.X. Wang ◽  
R.R. Adzic

Two new methods for monolayer-to-multileyer Pt deposition are presented. One involves Pt deposition by the replacement of an UPD metal monolayer on an electrode surface and the other the spontaneous deposition of Pt on Ru. The first method, exemplified by the replacement of a Cu monolayer on a Au(111) surface, occurs as a spontaneous irreversible redox reaction in which the Cu monolayer is oxidized by Pt cations, which are reduced and simultaneously deposited. The second method is illustrated by the deposition of Pt on a Ru(0001) surface and on carbon-supported Ru nanoparticles. This deposition takes place upon immersion of a UHV-prepared Ru(0001) crystal or Ru nanoparticles, reduced in H2, in a solution containing PtCl6 2- ions. The oxidation of Ru to RuOH by a local cell mechanism appears to be coupled with Pt deposition. This method facilitates the design of active Pt-Ru catalysts with ultimately low Pt loadings. Only a quarter of a monolayer of Pt on Ru nanoparticles yields an electrocatalyst with higher activity and CO tolerance for H2/CO oxidation than commercial Pt-Ru alloy electrocatalysts with considerably higher Pt loadings.


Author(s):  
Xuelan Yan ◽  
Tao Gan ◽  
Shaozhen Shi ◽  
Juan Du ◽  
Guohao Xu ◽  
...  

Potassium ions in the tunnel of MnO2 is demonstrated significantly enhancing the activity of surface oxygen species, which is favorable for preparing highly efficient Pt-based catalysts for low-temperature CO oxidation.


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