Non-Pincer Mn(I) Organometallics for the Selective Catalytic Hydrogenation of Nitriles to Primary Amines

ACS Catalysis ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 392-401 ◽  
Author(s):  
Jorge A. Garduño ◽  
Juventino J. García
Keyword(s):  
Catalytic Hydrogenation ◽  
Primary Amines ◽  
Hydrogenation Of Nitriles

Selective catalytic hydrogenation of nitriles to primary amines using iron pincer complexes

2016 ◽  
Vol 6 (13) ◽  
pp. 4768-4772 ◽  
Author(s):  
S. Lange ◽  
S. Elangovan ◽  
C. Cordes ◽  
A. Spannenberg ◽  
H. Jiao ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Primary Amines ◽  
Pincer Complexes ◽  
Pincer Complex ◽  
Hydrogenation Of Nitriles

The selective catalytic hydrogenation of nitriles to primary amines with the well-defined Fe(PNPCy) pincer complex 2 is reported.

scholarly journals Selective Heterogeneous Catalytic Hydrogenation of Nitriles to Primary Amines

2018 ◽  
Vol 62 (4) ◽  
Author(s):  
Krisztina Lévay ◽  
László Hegedűs
Keyword(s):  
Transition Metal ◽  
Catalytic Hydrogenation ◽  
Reaction Pathway ◽  
Selective Reduction ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Primary Amines ◽  
Heterogeneous Catalytic ◽  
Hydrogenation Of Nitriles ◽  
Heterogeneous Catalytic Hydrogenation

Primary amines are important intermediates, especially in the area of pharmaceutical, plastic and agrochemical industry. The heterogeneous catalytic hydrogenation of nitriles is one of the most frequently applied process for the synthesis of diverse amines. However, the control of the selectivity is a critical issue in this reaction. Over the past decade, many studies have been reported using heterogeneous transition metal catalysts for the selective reduction of nitriles to the corresponding primary amines. The type of the catalysts, especially, the chemical nature of metals in the catalysts is one of the most important factors to influence the selectivity, the reaction rate, and possibly also the reaction pathway and the deactivation of the catalyst. Thus, this review focuses on the heterogeneous transition metal catalysts and summarizes the recent developments achieved in the selective catalytic hydrogenation of nitriles to primary amines.

Hydrogenation of nitriles and imines for hydrogen storage

2018 ◽  
Vol 4 (3) ◽  
Author(s):  
Moran Feller
Keyword(s):  
Transition Metal ◽  
Hydrogen Storage ◽  
Catalytic Hydrogenation ◽  
Storage Capacity ◽  
Primary Amines ◽  
Hydrogen Storage Capacity ◽  
Hydrogenation Of Nitriles

Abstract This review focuses on the selective catalytic hydrogenation of nitriles to primary amines both homogeneously and heterogeneously with transition metal-based catalysts in the view of nitriles as hydrogen carriers. Nitriles can be reduced with two equivalents of H2 to primary amines, thus having a great potential to serve as liquid organic hydrogen carriers (LOHCs) for hydrogen storage. Imines are intermediates in the hydrogenation of nitriles to amines, thus they can also serve as potential LOHCs, however with a lower hydrogen storage capacity (HSC).

Selective catalytic transfer hydrogenation of nitriles to primary amines using Pd/C

2014 ◽  
Vol 4 (3) ◽  
pp. 629 ◽  
Author(s):  
Marcelo Vilches-Herrera ◽  
Svenja Werkmeister ◽  
Kathrin Junge ◽  
Armin Börner ◽  
Matthias Beller
Keyword(s):  
Transfer Hydrogenation ◽  
Primary Amines ◽  
Catalytic Transfer Hydrogenation ◽  
Catalytic Transfer ◽  
Hydrogenation Of Nitriles

Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Cobalt Pincer Complex

2015 ◽  
Vol 137 (28) ◽  
pp. 8888-8891 ◽  
Author(s):  
Arup Mukherjee ◽  
Dipankar Srimani ◽  
Subrata Chakraborty ◽  
Yehoshoa Ben-David ◽  
David Milstein
Keyword(s):  
Selective Hydrogenation ◽  
Primary Amines ◽  
Pincer Complex ◽  
Hydrogenation Of Nitriles
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