Selective catalytic hydrogenation of nitriles to primary amines using iron pincer complexes

2016 ◽  
Vol 6 (13) ◽  
pp. 4768-4772 ◽  
Author(s):  
S. Lange ◽  
S. Elangovan ◽  
C. Cordes ◽  
A. Spannenberg ◽  
H. Jiao ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Primary Amines ◽  
Pincer Complexes ◽  
Pincer Complex ◽  
Hydrogenation Of Nitriles

The selective catalytic hydrogenation of nitriles to primary amines with the well-defined Fe(PNPCy) pincer complex 2 is reported.

scholarly journals Highly selective hydrogenation of amides catalysed by a molybdenum pincer complex: scope and mechanism

2019 ◽  
Vol 10 (45) ◽  
pp. 10566-10576 ◽  
Author(s):  
Thomas Leischner ◽  
Lluis Artús Suarez ◽  
Anke Spannenberg ◽  
Kathrin Junge ◽  
Ainara Nova ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Selective Hydrogenation ◽  
Pincer Complexes ◽  
Pincer Complex ◽  
First Time

A series of molybdenum pincer complexes has been shown for the first time to be active in the catalytic hydrogenation of amides.

Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Cobalt Pincer Complex

2015 ◽  
Vol 137 (28) ◽  
pp. 8888-8891 ◽  
Author(s):  
Arup Mukherjee ◽  
Dipankar Srimani ◽  
Subrata Chakraborty ◽  
Yehoshoa Ben-David ◽  
David Milstein
Keyword(s):  
Selective Hydrogenation ◽  
Primary Amines ◽  
Pincer Complex ◽  
Hydrogenation Of Nitriles

ChemInform Abstract: Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Cobalt Pincer Complex.

ChemInform ◽  
2015 ◽  
Vol 46 (52) ◽  
pp. no-no
Author(s):  
Arup Mukherjee ◽  
Dipankar Srimani ◽  
Subrata Chakraborty ◽  
Yehoshoa Ben-David ◽  
David Milstein
Keyword(s):  
Selective Hydrogenation ◽  
Primary Amines ◽  
Pincer Complex ◽  
Hydrogenation Of Nitriles

Low-Pressure Hydrogenation of Nitriles to Primary Amines Catalyzed by Ruthenium Pincer Complexes. Scope and mechanism

ChemCatChem ◽  
2017 ◽  
Vol 9 (4) ◽  
pp. 559-563 ◽  
Author(s):  
Arup Mukherjee ◽  
Dipankar Srimani ◽  
Yehoshoa Ben-David ◽  
David Milstein
Keyword(s):  
Low Pressure ◽  
Primary Amines ◽  
Pincer Complexes ◽  
Hydrogenation Of Nitriles

scholarly journals Cover Feature: Synthesis of Molybdenum Pincer Complexes and Their Application in the Catalytic Hydrogenation of Nitriles (ChemCatChem 18/2020)

ChemCatChem ◽  
2020 ◽  
Vol 12 (18) ◽  
pp. 4448-4448
Author(s):  
Thomas Leischner ◽  
Anke Spannenberg ◽  
Kathrin Junge ◽  
Matthias Beller
Keyword(s):  
Catalytic Hydrogenation ◽  
Pincer Complexes ◽  
Hydrogenation Of Nitriles

scholarly journals Selective Heterogeneous Catalytic Hydrogenation of Nitriles to Primary Amines

2018 ◽  
Vol 62 (4) ◽  
Author(s):  
Krisztina Lévay ◽  
László Hegedűs
Keyword(s):  
Transition Metal ◽  
Catalytic Hydrogenation ◽  
Reaction Pathway ◽  
Selective Reduction ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Primary Amines ◽  
Heterogeneous Catalytic ◽  
Hydrogenation Of Nitriles ◽  
Heterogeneous Catalytic Hydrogenation

Primary amines are important intermediates, especially in the area of pharmaceutical, plastic and agrochemical industry. The heterogeneous catalytic hydrogenation of nitriles is one of the most frequently applied process for the synthesis of diverse amines. However, the control of the selectivity is a critical issue in this reaction. Over the past decade, many studies have been reported using heterogeneous transition metal catalysts for the selective reduction of nitriles to the corresponding primary amines. The type of the catalysts, especially, the chemical nature of metals in the catalysts is one of the most important factors to influence the selectivity, the reaction rate, and possibly also the reaction pathway and the deactivation of the catalyst. Thus, this review focuses on the heterogeneous transition metal catalysts and summarizes the recent developments achieved in the selective catalytic hydrogenation of nitriles to primary amines.

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