Catalytic hydrogenation of nitriles and dehydrogenation of amines with the rhodium(I) hydrido compounds [RhH(PPri3)3] and [Rh2H2(µ-N2){P(cyclohexyl)3}4]

1979 ◽  
pp. 870-871 ◽  
Author(s):  
Toshikatsu Yoshida ◽  
Tamon Okano ◽  
Sei Otsuka
Keyword(s):  
Catalytic Hydrogenation ◽  
Hydrogenation Of Nitriles

Recent Achievements in the Hydrogenation of Nitriles Catalyzed by Transitional Metals

2019 ◽  
Vol 23 (18) ◽  
pp. 1881-1900 ◽  
Author(s):  
Krisztina Lévay ◽  
László Hegedűs
Keyword(s):  
Transition Metal ◽  
Homogeneous Catalysis ◽  
Catalytic Hydrogenation ◽  
Selective Reduction ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Transitional Metals ◽  
Heterogeneous Catalytic ◽  
Hydrogenation Of Nitriles ◽  
Heterogeneous Catalytic Hydrogenation

Amines are important and valuable intermediates in the pharmaceutical, plastic and agrochemical industry. Hence, there is an increasing interest in developing improved process for the synthesis of amines. The heterogeneous catalytic hydrogenation of nitriles is one of the most frequently applied methods for the synthesis of diverse amines, but the homogeneous catalysis has also received a growing attention from the catalysis community. This mini-review provides an overview of the recent achievements in the selective reduction of nitriles using both homogeneous and heterogeneous transition metal catalysts.

Selective catalytic hydrogenation of nitriles to primary amines using iron pincer complexes

2016 ◽  
Vol 6 (13) ◽  
pp. 4768-4772 ◽  
Author(s):  
S. Lange ◽  
S. Elangovan ◽  
C. Cordes ◽  
A. Spannenberg ◽  
H. Jiao ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Primary Amines ◽  
Pincer Complexes ◽  
Pincer Complex ◽  
Hydrogenation Of Nitriles

The selective catalytic hydrogenation of nitriles to primary amines with the well-defined Fe(PNPCy) pincer complex 2 is reported.

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