Reactivity of Transition-Metal Complexes in Excited States: C–O Bond Coupling Reductive Elimination of a Ni(II) Complex Is Elicited by the Metal-to-Ligand Charge Transfer State

ACS Catalysis ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 1-6 ◽  
Author(s):  
Pengchen Ma ◽  
Shaohong Wang ◽  
Hui Chen
Keyword(s):  
Charge Transfer ◽  
Transition Metal ◽  
Metal Complexes ◽  
Excited States ◽  
Transition Metal Complexes ◽  
Reductive Elimination ◽  
Charge Transfer State ◽  
Ligand Charge Transfer ◽  
Transfer State

Electron spin-controlled charge transfer and the resulting long-lived charge transfer state: from transition metal complexes to organic compounds

2021 ◽  
Vol 50 (1) ◽  
pp. 59-67
Author(s):  
Xue Zhang ◽  
Xi Chen ◽  
Jianzhang Zhao
Keyword(s):  
Charge Transfer ◽  
Transition Metal ◽  
Metal Complexes ◽  
Organic Compounds ◽  
Transition Metal Complexes ◽  
Electron Spin ◽  
Charge Transfer State ◽  
Transfer State

Electron spin control is promising to prolong the charge transfer (CT) state lifetime based on spin forbidden 3CT → S0.

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