Electroabsorption Spectroscopy of Charge-Transfer States of Transition-Metal Complexes. 2. Metal-to-Ligand and Ligand-to-Metal Charge-Transfer Excited States of Pentaammineruthenium Complexes1

1996 ◽  
Vol 100 (20) ◽  
pp. 8157-8169 ◽  
Author(s):  
Yeung-gyo K. Shin ◽  
Bruce S. Brunschwig ◽  
Carol Creutz ◽  
Norman Sutin
Keyword(s):  
Charge Transfer ◽  
Transition Metal ◽  
Metal Complexes ◽  
Excited States ◽  
Transition Metal Complexes ◽  
Metal Charge ◽  
Electroabsorption Spectroscopy ◽  
Metal Charge Transfer

Ligand(s)-to-metal charge transfer as a factor controlling the equilibrium constants of late first-row transition metal complexes: revealing the Irving–Williams thermodynamical series

2015 ◽  
Vol 17 (2) ◽  
pp. 805-811 ◽  
Author(s):  
Pradeep R. Varadwaj ◽  
Arpita Varadwaj ◽  
Bih-Yaw Jin
Keyword(s):  
Charge Transfer ◽  
Transition Metal ◽  
Metal Ions ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Equilibrium Constants ◽  
Bivalent Metal ◽  
Metal Charge ◽  
Bivalent Metal Ions ◽  
Metal Charge Transfer

Ligand(s)-to-metal charge transfer obtained from QTAIM charges unravel the Irving–William series for the equilibrium constants of late first-row bivalent metal ions.

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