scholarly journals Arylammonium-Assisted Reduction of the Open-Circuit Voltage Deficit in Wide-Bandgap Perovskite Solar Cells: The Role of Suppressed Ion Migration

2020 ◽  
Vol 5 (8) ◽  
pp. 2560-2568 ◽  
Author(s):  
Cong Chen ◽  
Zhaoning Song ◽  
Chuanxiao Xiao ◽  
Rasha A. Awni ◽  
Canglang Yao ◽  
...  
Nanophotonics ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Rui He ◽  
Tingting Chen ◽  
Zhipeng Xuan ◽  
Tianzhen Guo ◽  
Jincheng Luo ◽  
...  

Abstract Wide-bandgap (wide-E g , ∼1.7 eV or higher) perovskite solar cells (PSCs) have attracted extensive attention due to the great potential of fabricating high-performance perovskite-based tandem solar cells via combining with low-bandgap absorbers, which is considered promising to exceed the Shockley–Queisser efficiency limit. However, inverted wide-E g PSCs with a minimized open-circuit voltage (V oc) loss, which are more suitable to prepare all-perovskite tandem devices, are still lacking study. Here, we report a strategy of adding 1,3,5-tris (bromomethyl) benzene (TBB) into wide-E g perovskite absorber to passivate the perovskite film, leading to an enhanced average V oc. Incorporation of TBB prolongs carrier lifetimes in wide-E g perovskite due to reduction of defects in perovskites and makes a better energy level matching between perovskite absorber and electron transport layer. As a result, we achieve the power conversion efficiency of 17.12% for our inverted TBB-doped PSC with an enhanced V oc of 1.19 V, compared with that (16.14%) for the control one (1.14 V).


2019 ◽  
Vol 9 (21) ◽  
pp. 1970079 ◽  
Author(s):  
Saba Gharibzadeh ◽  
Bahram Abdollahi Nejand ◽  
Marius Jakoby ◽  
Tobias Abzieher ◽  
Dirk Hauschild ◽  
...  

2020 ◽  
Vol 8 (21) ◽  
pp. 7143-7148
Author(s):  
Christos Zervos ◽  
Marinos Tountas ◽  
Konstantinos Chatzimanolis ◽  
Christos Polyzoidis ◽  
Emmanuel Kymakis

An alternate use of PEAI for enhancing the performance of inverted perovskite solar cells is demonstrated, by employing it as an anti-solvent during the perovskite fabrication process. The results show an enhancement of the open-circuit voltage as compared to the PEAI post treatment.


Solar RRL ◽  
2018 ◽  
Vol 2 (8) ◽  
pp. 1800083 ◽  
Author(s):  
Xiaowen Hu ◽  
Xiao-Fang Jiang ◽  
Xiaobo Xing ◽  
Li Nian ◽  
Xiaoyang Liu ◽  
...  

Nano Energy ◽  
2019 ◽  
Vol 61 ◽  
pp. 141-147 ◽  
Author(s):  
Cong Chen ◽  
Zhaoning Song ◽  
Chuanxiao Xiao ◽  
Dewei Zhao ◽  
Niraj Shrestha ◽  
...  

2016 ◽  
Vol 9 (11) ◽  
pp. 3472-3481 ◽  
Author(s):  
Tomas Leijtens ◽  
Giles E. Eperon ◽  
Alex J. Barker ◽  
Giulia Grancini ◽  
Wei Zhang ◽  
...  

We show that trapped electrons recombine with free holes unexpectedly slowly, on microsecond time scales, relaxing the limit on obtainable open circuit voltage.


2019 ◽  
Vol 9 (21) ◽  
pp. 1803699 ◽  
Author(s):  
Saba Gharibzadeh ◽  
Bahram Abdollahi Nejand ◽  
Marius Jakoby ◽  
Tobias Abzieher ◽  
Dirk Hauschild ◽  
...  

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