Conversion of Waste Plastic Packings to Carbon Nanomaterials: Investigation into Catalyst Material, Waste Type, and Product Applications

Author(s):  
Dingding Yao ◽  
He Li ◽  
Babu Cadiam Mohan ◽  
Arun Kumar Prabhakar ◽  
Yanjun Dai ◽  
...  
2018 ◽  
Author(s):  
Erik Leonhardt ◽  
Jeff M. Van Raden ◽  
David Miller ◽  
Lev N. Zakharov ◽  
Benjamin Aleman ◽  
...  

Extended carbon nanostructures, such as carbon nanotubes (CNTs), exhibit remarkable properties but are difficult to synthesize uniformly. Herein, we present a new class of carbon nanomaterials constructed via the bottom-up self-assembly of cylindrical, atomically-precise small molecules. Guided by supramolecular design principles and circle packing theory, we have designed and synthesized a fluorinated nanohoop that, in the solid-state, self-assembles into nanotube-like arrays with channel diameters of precisely 1.63 nm. A mild solution-casting technique is then used to construct vertical “forests” of these arrays on a highly-ordered pyrolytic graphite (HOPG) surface through epitaxial growth. Furthermore, we show that a basic property of nanohoops, fluorescence, is readily transferred to the bulk phase, implying that the properties of these materials can be directly altered via precise functionalization of their nanohoop building blocks. The strategy presented is expected to have broader applications in the development of new graphitic nanomaterials with π-rich cavities reminiscent of CNTs.


Recycling ◽  
2019 ◽  
Vol 4 (1) ◽  
pp. 3 ◽  
Author(s):  
Linda Godfrey

With changing consumption patterns, growing populations and increased urbanisation, developing countries face significant challenges with regards to waste management. Waste plastic is a particularly problematic one, with single-use plastic leaking into the environment, including the marine environment, at an unprecedented rate. Around the world, countries are taking action to minimise these impacts, including banning single-use plastics; changing petroleum-based plastics to alternative bio-benign products such as paper, glass or biodegradable plastics; and improving waste collection systems to ensure that all waste is appropriately collected and reprocessed or safely disposed. However, these “solutions” are often met with resistance, from business, government or civil society, due to the intended and unintended consequences, leaving many questioning the most appropriate solution to reducing the leakage. This paper argues that there is no one single solution to addressing the leakage of plastic into the environment, but that the solution is likely to be a combination of the three approaches, based on local considerations.


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