Hollow Sphere TiO2–ZrO2 Prepared by Self-Assembly with Polystyrene Colloidal Template for Both Photocatalytic Degradation and H2 Evolution from Water Splitting

2016 ◽  
Vol 4 (4) ◽  
pp. 2037-2046 ◽  
Author(s):  
Jianqi Zhang ◽  
Li Li ◽  
Zhixin Xiao ◽  
Di Liu ◽  
Shuang Wang ◽  
...  
2016 ◽  
Vol 52 (95) ◽  
pp. 13787-13790 ◽  
Author(s):  
Peng Huang ◽  
Chao Qin ◽  
Yu Zhou ◽  
Yu-Mei Hong ◽  
Xin-Long Wang ◽  
...  

Two unprecedented polytantalotungstates, 1 and 2 based on the largest {Ta18} and {Ta18Yb2} clusters, respectively, were synthesized. 1 and 2 exhibit significant UV photocatalytic water splitting activity.


Materials ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1338 ◽  
Author(s):  
Klara Perović ◽  
Francis M. dela Rosa ◽  
Marin Kovačić ◽  
Hrvoje Kušić ◽  
Urška Lavrenčič Štangar ◽  
...  

Clean water and the increased use of renewable energy are considered to be two of the main goals in the effort to achieve a sustainable living environment. The fulfillment of these goals may include the use of solar-driven photocatalytic processes that are found to be quite effective in water purification, as well as hydrogen generation. H2 production by water splitting and photocatalytic degradation of organic pollutants in water both rely on the formation of electron/hole (e−/h+) pairs at a semiconducting material upon its excitation by light with sufficient photon energy. Most of the photocatalytic studies involve the use of TiO2 and well-suited model compounds, either as sacrificial agents or pollutants. However, the wider application of this technology requires the harvesting of a broader spectrum of solar irradiation and the suppression of the recombination of photogenerated charge carriers. These limitations can be overcome by the use of different strategies, among which the focus is put on the creation of heterojunctions with another narrow bandgap semiconductor, which can provide high response in the visible light region. In this review paper, we report the most recent advances in the application of TiO2 based heterojunction (semiconductor-semiconductor) composites for photocatalytic water treatment and water splitting. This review article is subdivided into two major parts, namely Photocatalytic water treatment and Photocatalytic water splitting, to give a thorough examination of all achieved progress. The first part provides an overview on photocatalytic degradation mechanism principles, followed by the most recent applications for photocatalytic degradation and mineralization of contaminants of emerging concern (CEC), such as pharmaceuticals and pesticides with a critical insight into removal mechanism, while the second part focuses on fabrication of TiO2-based heterojunctions with carbon-based materials, transition metal oxides, transition metal chalcogenides, and multiple composites that were made of three or more semiconductor materials for photocatalytic water splitting.


Author(s):  
Chao Zhang ◽  
Baoquan Liu ◽  
Weiping Li ◽  
Xiangxue Liu ◽  
Ke Wang ◽  
...  

Well-designed honeycomb Co3O4@CdS (H-Co3O4@CdS) was fabricated via a one-step strategy for efficient water splitting. During the decoration of CdS, honeycomb Co3O4 (H-Co3O4) with macropore was formed simultaneously. H-Co3O4 could enhance...


2017 ◽  
Vol 316 ◽  
pp. 778-789 ◽  
Author(s):  
Shuying Dong ◽  
Xuhui Ding ◽  
Teng Guo ◽  
Xiaoping Yue ◽  
Xiao Han ◽  
...  

Author(s):  
Xueru Chen ◽  
Xin Li ◽  
Xue Li ◽  
Huimin Lu ◽  
Lei Wang ◽  
...  

Vacancy engineering and morphology construction were integrated simultaneously by the self-assembly of melamine (MA) and cyanuric acid (CA) in the presence of P123 and H2SO4, which contributed to the hexagonal...


Cellulose ◽  
2020 ◽  
Vol 27 (9) ◽  
pp. 5241-5253 ◽  
Author(s):  
Lingfeng Yan ◽  
Baojiang Liu ◽  
Weiya Li ◽  
Tao Zhao ◽  
Yatao Wang ◽  
...  

2019 ◽  
Vol 55 (86) ◽  
pp. 12900-12903 ◽  
Author(s):  
Lihang Tong ◽  
Liteng Ren ◽  
Ao Fu ◽  
Defa Wang ◽  
Lequan Liu ◽  
...  

One-nanometre-thick carbon cage encapsulated copper nanoparticles synthesized through chemical vapour deposition showed remarkable stability in photocatalysis and thermocatalysis.


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