Preferential solvation and the role of solvent in kinetics. Examples from ligand substitution reactions

Cooper H. Langford; James P. K. Tong

doi:10.1021/ar50115a005

Preferential solvation and the role of solvent in kinetics. Examples from ligand substitution reactions

Accounts of Chemical Research ◽

10.1021/ar50115a005 ◽

1977 ◽

Vol 10 (7) ◽

pp. 258-264 ◽

Cited By ~ 30

Author(s):

Cooper H. Langford ◽

James P. K. Tong

Keyword(s):

Preferential Solvation ◽

Ligand Substitution ◽

Substitution Reactions ◽

Role Of Solvent ◽

Ligand Substitution Reactions

Rhodium(III) pentamethyl cyclopentadienyl complexes incorporating 1-(4-cyanophenyl)-imidazole: role of solvent in ligand substitution reactions

Journal of Organometallic Chemistry ◽

10.1016/j.jorganchem.2004.10.018 ◽

2005 ◽

Vol 690 (3) ◽

pp. 647-652 ◽

Cited By ~ 11

Author(s):

Sanjay Kumar Singh ◽

Manoj Trivedi ◽

Manish Chandra ◽

Daya Shankar Pandey

Keyword(s):

Ligand Substitution ◽

Substitution Reactions ◽

Cyclopentadienyl Complexes ◽

Role Of Solvent ◽

Ligand Substitution Reactions

Mechanistic Studies on Fast Ligand Substitution Reactions of Pt(II) in Different Ionic Liquids: Role of Solvent Polarity and Ion-Pair Formation

Inorganic Chemistry ◽

10.1021/ic702420v ◽

2008 ◽

Vol 47 (16) ◽

pp. 7121-7132 ◽

Cited By ~ 21

Author(s):

Svetlana Begel ◽

Peter Illner ◽

Simon Kern ◽

Ralph Puchta ◽

Rudi van Eldik

Keyword(s):

Ionic Liquids ◽

Solvent Polarity ◽

Ligand Substitution ◽

Ion Pair ◽

Pair Formation ◽

Mechanistic Studies ◽

Substitution Reactions ◽

Ion Pair Formation ◽

Role Of Solvent

Ligand substitution reactions of (bidentato-O,O and −O,N) bis(ethylenediamine)cobalt(III) complexes with ethylenediamine catalyzed by photoexcited tris(2,2′-bipyridine)ruthenium(II) complex: The role of circularly polarized light in photoirradiation

Polyhedron ◽

10.1016/s0277-5387(00)81039-6 ◽

1987 ◽

Vol 6 (3) ◽

pp. 651-654 ◽

Cited By ~ 4

Author(s):

Masahiko Ishikawa ◽

Ken-Ichi Okamoto ◽

Jinsai Hidaka ◽

Hisahiko Einaga

Keyword(s):

Polarized Light ◽

Ligand Substitution ◽

Substitution Reactions ◽

Circularly Polarized Light ◽

Circularly Polarized ◽

Ligand Substitution Reactions

Fe3-triangle opening and closing by a single two-electron process: role of the one-electron-reduced intermediate in the electrocatalytic ligand substitution reactions of Fe3(CO)9(.mu.3-PMn(CO)2Cp)2

Organometallics ◽

10.1021/om00036a027 ◽

1993 ◽

Vol 12 (12) ◽

pp. 4854-4862 ◽

Cited By ~ 6

Author(s):

Yoshihiro Koide ◽

Cynthia K. Schauer

Keyword(s):

Ligand Substitution ◽

Substitution Reactions ◽

Electron Process ◽

The One ◽

Opening And Closing ◽

Ligand Substitution Reactions

1700657: Impact of chloride concentration on ligand substitution reactions of zinc(II) complexes with biologically relevant nitrogen nucleophiles-ESI

Progress in Reaction Kinetics and Mechanism ◽

10.3184/146867818x15319903829245 ◽

2018 ◽

Keyword(s):

Chloride Concentration ◽

Ligand Substitution ◽

Substitution Reactions ◽

Biologically Relevant ◽

Nitrogen Nucleophiles ◽

Ligand Substitution Reactions

Physical properties, ligand substitution reactions, and biological activity of Co(iii)-Schiff base complexes

Dalton Transactions ◽

10.1039/c8dt04606a ◽

2019 ◽

Vol 48 (18) ◽

pp. 5987-6002 ◽

Cited By ~ 5

Author(s):

A. Paden King ◽

Hendryck A. Gellineau ◽

Samantha N. MacMillan ◽

Justin J. Wilson

Keyword(s):

Biological Activity ◽

Schiff Base ◽

Physical Properties ◽

Ligand Exchange ◽

Ligand Substitution ◽

Schiff Base Complexes ◽

Substitution Reactions ◽

Anticancer Properties ◽

Ligand Substitution Reactions

A subset of fluorinated Co(iii) Schiff base complexes was synthesized, and their structural, ligand exchange, and anticancer properties were investigated.

Dinuclear nitrido-bridged ruthenium complexes bearing diimine ligands

Dalton Transactions ◽

10.1039/c7dt03085a ◽

2017 ◽

Vol 46 (41) ◽

pp. 14256-14263 ◽

Cited By ~ 3

Author(s):

Julie Urgiles ◽

Sarah R. Nathan ◽

Samantha N. MacMillan ◽

Justin J. Wilson

Keyword(s):

Calcium Uptake ◽

Ruthenium Complexes ◽

Ligand Substitution ◽

Mitochondrial Calcium ◽

Substitution Reactions ◽

Uptake Inhibition ◽

Diimine Ligands ◽

Mitochondrial Calcium Uptake ◽

Ligand Substitution Reactions

Nitrido-bridged ruthenium complexes are synthesized via ligand substitution reactions and evaluated for mitochondrial calcium uptake inhibition.

Synthetic analogs of the active sites of iron-sulfur proteins. X. Kinetics and mechanism of the ligand substitution reactions of arylthiols with the tetranuclear clusters [Fe4S4(SR)4]2-

Journal of the American Chemical Society ◽

10.1021/ja00836a011 ◽

1975 ◽

Vol 97 (3) ◽

pp. 528-533 ◽

Cited By ~ 37

Author(s):

Gary R. Dukes ◽

R. H. Holm

Keyword(s):

Active Sites ◽

Ligand Substitution ◽

Kinetics And Mechanism ◽

Substitution Reactions ◽

Synthetic Analogs ◽

Iron Sulfur ◽

Iron Sulfur Proteins ◽

Tetranuclear Clusters ◽

Ligand Substitution Reactions

Kinetic and spectrophotometric determination of trace zinc(II) in the presence of a large amount of lead(II) using ligand-substitution reactions of their metalloporphyrins with EDTA.

Analytical Sciences ◽

10.2116/analsci.5.719 ◽

1989 ◽

Vol 5 (6) ◽

pp. 719-724 ◽

Cited By ~ 8

Author(s):

Masaaki TABATA ◽

Naoko KAJIHARA

Keyword(s):

Spectrophotometric Determination ◽

Ligand Substitution ◽

Substitution Reactions ◽

Ligand Substitution Reactions

Axial ligand substitution reactions of iron(II) phthalocyanine adducts

Inorganic Chemistry ◽

10.1021/ic50209a065 ◽

1980 ◽

Vol 19 (7) ◽

pp. 2162-2165 ◽

Cited By ~ 23

Author(s):

Jens Martinsen ◽

Michael Miller ◽

Daria Trojan ◽

D. A. Sweigart

Keyword(s):

Ligand Substitution ◽

Axial Ligand ◽

Substitution Reactions ◽

Ligand Substitution Reactions