scholarly journals Partial Steps of Charge Translocation in the Nonpumping N139L Mutant ofRhodobacter sphaeroidesCytochromecOxidase with a Blocked D-Channel

Biochemistry ◽  
2010 ◽  
Vol 49 (14) ◽  
pp. 3060-3073 ◽  
Author(s):  
Sergey A. Siletsky ◽  
Jiapeng Zhu ◽  
Robert B. Gennis ◽  
Alexander A. Konstantinov
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1992 ◽  
Vol 671 (1 Ion-Motive AT) ◽  
pp. 170-188 ◽  
Author(s):  
M. STENGELIN ◽  
A. EISENRAUCH ◽  
K. FENDLER ◽  
G. NAGEL ◽  
H. T. W. HIJDEN ◽  
...  
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2000 ◽  
Vol 28 (5) ◽  
pp. A469-A469 ◽  
Author(s):  
S. Siletsky ◽  
D. Zaslavsky ◽  
I. Smirnova ◽  
A. Kaulen ◽  
A. Konstantinov

Author(s):  
Helen J. Zeng ◽  
Mark A. Johnson

The ease with which the pH is routinely determined for aqueous solutions masks the fact that the cationic product of Arrhenius acid dissolution, the hydrated proton, or H+(aq), is a remarkably complex species. Here, we review how results obtained over the past 30 years in the study of H+⋅(H2O) n cluster ions isolated in the gas phase shed light on the chemical nature of H+(aq). This effort has also revealed molecular-level aspects of the Grotthuss relay mechanism for positive-charge translocation in water. Recently developed methods involving cryogenic cooling in radiofrequency ion traps and the application of two-color, infrared–infrared (IR–IR) double-resonance spectroscopy have established a clear picture of how local hydrogen-bond topology drives the diverse spectral signatures of the excess proton. This information now enables a new generation of cluster studies designed to unravel the microscopic mechanics underlying the ultrafast relaxation dynamics displayed by H+(aq). Expected final online publication date for the Annual Review of Physical Chemistry, Volume 72 is April 2021. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.


1997 ◽  
Vol 1318 (1-2) ◽  
pp. 299-306 ◽  
Author(s):  
Mårten Wikström ◽  
Joel E Morgan ◽  
Michael I Verkhovsky

1997 ◽  
Vol 834 (1 Na/K-ATPase a) ◽  
pp. 231-243 ◽  
Author(s):  
R. F. RAKOWSKI ◽  
FRANCISCO BEZANILLA ◽  
P. DE WEER ◽  
DAVID C. GADSBY ◽  
MIGUEL HOLMGREN ◽  
...  
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2009 ◽  
Vol 285 (5) ◽  
pp. 3103-3113 ◽  
Author(s):  
Ryan M. McGuire ◽  
Haiying Liu ◽  
Fred A. Pereira ◽  
Robert M. Raphael

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