Isotope Effects and Reaction Mechanisms

1975 ◽  
pp. 163-183 ◽  
Author(s):  
V. J. SHINER
Keyword(s):  
Reaction Mechanisms ◽  
Isotope Effects

ChemInform Abstract: METHYL-D(3) ISOTOPE EFFECTS, ALPHA-METHYL HYDROGEN RATE EFFECTS, AND THE ANALYSIS OF SOME SOLVOLYTIC REACTION MECHANISMS

1975 ◽  
Vol 6 (28) ◽  
pp. no-no
Author(s):  
ROBERT D. FISHER ◽  
RICHARD C. SEIB ◽  
VERNON J. JUN. SHINER ◽  
IVANKA SZELE ◽  
MIHOVIL TOMIC ◽  
...  
Keyword(s):  
Reaction Mechanisms ◽  
Isotope Effects ◽  
Rate Effects

scholarly journals How coverage influences thermodynamic and kinetic isotope effects for H2/D2 dissociative adsorption on transition metals

2020 ◽  
Vol 10 (3) ◽  
pp. 671-689 ◽  
Author(s):  
Benjamin W. J. Chen ◽  
Manos Mavrikakis
Keyword(s):  
Transition Metals ◽  
Reaction Mechanisms ◽  
Hydrogen Isotope ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Dissociative Adsorption ◽  
Kinetic Isotope

Hydrogen isotope effects are influenced by adsorbate coverage: at high coverages, isotope effects are lower than at low coverages. This helps to rationalize observed isotope effects, allowing more precise elucidation of reaction mechanisms.

Methyl-d3 isotope effects, .alpha.-methyl hydrogen rate effects, and the analysis of some solvolytic reaction mechanisms

1975 ◽  
Vol 97 (9) ◽  
pp. 2408-2413 ◽  
Author(s):  
Robert D. Fisher ◽  
Richard C. Seib ◽  
Vernon J. Shiner ◽  
Ivanka Szele ◽  
Mihovil Tomic ◽  
...  
Keyword(s):  
Reaction Mechanisms ◽  
Isotope Effects ◽  
Rate Effects
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