ChemInform Abstract: Ene Reaction Mechanisms. Part 3. Intermolecular and Intramolecular Kinetic Isotope Effects (KIE) for Some Ene Reactions of Hetero Enophiles.

1986 ◽  
Vol 17 (25) ◽  
Author(s):  
W. STARFLINGER ◽  
G. KRESZE ◽  
K. HUSS
Keyword(s):  
Reaction Mechanisms ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Ene Reactions ◽  
Ene Reaction ◽  
Kinetic Isotope

Intramolecular and Intermolecular Kinetic Isotope Effects (KIE) in the Nitrosoarene Ene Reaction:  Experimental Evidence for Reversible Intermediate Formation

2003 ◽  
Vol 68 (6) ◽  
pp. 2420-2425 ◽  
Author(s):  
Waldemar Adam ◽  
Oliver Krebs ◽  
Michael Orfanopoulos ◽  
Manolis Stratakis ◽  
Georgios C. Vougioukalakis
Keyword(s):  
Experimental Evidence ◽  
Isotope Effects ◽  
Intermediate Formation ◽  
Kinetic Isotope Effects ◽  
Ene Reaction ◽  
Kinetic Isotope

scholarly journals How coverage influences thermodynamic and kinetic isotope effects for H2/D2 dissociative adsorption on transition metals

2020 ◽  
Vol 10 (3) ◽  
pp. 671-689 ◽  
Author(s):  
Benjamin W. J. Chen ◽  
Manos Mavrikakis
Keyword(s):  
Transition Metals ◽  
Reaction Mechanisms ◽  
Hydrogen Isotope ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Dissociative Adsorption ◽  
Kinetic Isotope

Hydrogen isotope effects are influenced by adsorbate coverage: at high coverages, isotope effects are lower than at low coverages. This helps to rationalize observed isotope effects, allowing more precise elucidation of reaction mechanisms.

Sign in / Sign up

Export Citation Format

Share Document