11C/14C kinetic isotope effects. A method for investigation of enzyme and organic reaction mechanisms

1989 ◽  
Vol 26 (1-12) ◽  
pp. 77-78
Author(s):  
S. Axelsson ◽  
O. Matsson ◽  
B. Långström
Keyword(s):  
Reaction Mechanisms ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Organic Reaction ◽  
Kinetic Isotope ◽  
Organic Reaction Mechanisms

scholarly journals How coverage influences thermodynamic and kinetic isotope effects for H2/D2 dissociative adsorption on transition metals

2020 ◽  
Vol 10 (3) ◽  
pp. 671-689 ◽  
Author(s):  
Benjamin W. J. Chen ◽  
Manos Mavrikakis
Keyword(s):  
Transition Metals ◽  
Reaction Mechanisms ◽  
Hydrogen Isotope ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Dissociative Adsorption ◽  
Kinetic Isotope

Hydrogen isotope effects are influenced by adsorbate coverage: at high coverages, isotope effects are lower than at low coverages. This helps to rationalize observed isotope effects, allowing more precise elucidation of reaction mechanisms.

Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms

2011 ◽  
Vol 111 (8) ◽  
pp. 4857-4963 ◽  
Author(s):  
Mar Gómez-Gallego ◽  
Miguel A. Sierra
Keyword(s):  
Reaction Mechanisms ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope
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