Kinetic Isotope Effects and rganic Reaction Mechanisms

Science ◽  
1966 ◽  
Vol 154 (3757) ◽  
pp. 1616-1621 ◽  
Author(s):  
M. J. Goldstein
Keyword(s):  
Reaction Mechanisms ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope

scholarly journals How coverage influences thermodynamic and kinetic isotope effects for H2/D2 dissociative adsorption on transition metals

2020 ◽  
Vol 10 (3) ◽  
pp. 671-689 ◽  
Author(s):  
Benjamin W. J. Chen ◽  
Manos Mavrikakis
Keyword(s):  
Transition Metals ◽  
Reaction Mechanisms ◽  
Hydrogen Isotope ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Dissociative Adsorption ◽  
Kinetic Isotope

Hydrogen isotope effects are influenced by adsorbate coverage: at high coverages, isotope effects are lower than at low coverages. This helps to rationalize observed isotope effects, allowing more precise elucidation of reaction mechanisms.

Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms

2011 ◽  
Vol 111 (8) ◽  
pp. 4857-4963 ◽  
Author(s):  
Mar Gómez-Gallego ◽  
Miguel A. Sierra
Keyword(s):  
Reaction Mechanisms ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope

Theoretical Simulations of Heavy-Atom Kinetic Isotope Effects in Aliphatic Claisen Rearrangement

2020 ◽  
Vol 124 (51) ◽  
pp. 10678-10686
Author(s):  
Yuqing Xu ◽  
Kin-Yiu Wong ◽  
Meishan Wang ◽  
Desheng Liu ◽  
Wenkai Zhao ◽  
...  
Keyword(s):  
Claisen Rearrangement ◽  
Isotope Effects ◽  
Heavy Atom ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope ◽  
Theoretical Simulations
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