scholarly journals A Three-Dimensional Mixed-Ligand Coordination Polymer Featuring Strongly Antiferromagnetically Coupled Dinuclear Copper Paddlewheels Linked into a 6-Connected Self-Penetrated Network

2008 ◽  
Vol 8 (12) ◽  
pp. 4602-4602 ◽  
Author(s):  
David P. Martin ◽  
Ronald M. Supkowski ◽  
Robert L. LaDuca

2021 ◽  
Vol 25 (7) ◽  
pp. 147-156
Author(s):  
Ajeet Kumar Maurya ◽  
Ashish Kumar Srivastava ◽  
Krishna Srivastava ◽  
Jagdish Prasad

Four mixed-ligand coordination polymer complexes of cobalt(II), copper(II), zinc(II), and cadmium(II) were synthesized by solvothermal method in 1:1:1 metal: 4,4’-bipy: 2,5-pdc molar ratio using 2,5-pyridinedicarboxylic acid (2,5-pdc) and 4,4’-bipyridine (4,4’-bipy). These complexes are viz; 1. [Co2(4,4'-bipy)(2,5-pdc)2(H2O)4]n 2. [Cu2(4,4'-bipy) (2,5-pdc)2]n 3. [Zn2(4,4'-bipy)(2,5-pdc)2(H2O)4]n and 4. [Cd3(4,4'-bipy)(2,5-pdc)2(OOCCH3)2(H2O)4]n.. All these complexes (1-4) have been characterized by elemental analyses (C,H,N), FT-IR-spectra, thermal analyses (TGA/DTA/DTG), fluorescence spectra and powder X-ray diffraction (PXRD) analyses to arrive at conclusion regarding their geometrical structure.







2020 ◽  
Vol 49 (42) ◽  
pp. 14975-14984
Author(s):  
Bradley Westwater ◽  
Hayleigh J. Lloyd ◽  
Inigo J. Vitorica-Yrezabal ◽  
Angela Fong ◽  
Patrick McMaster ◽  
...  

An unexpected novel energetic material was found in seed crystal-controlled CuCl2 – Na(N4C-NO2) – sodium ascorbate reduction reactions.





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