On-Site Profiling and Speciation of Polycyclic Aromatic Hydrocarbons at Manufactured Gas Plant Sites by a High Temperature Transfer Line, Membrane Inlet Probe Coupled to a Photoionization Detector and Gas Chromatograph/Mass Spectrometer

2008 ◽  
Vol 42 (4) ◽  
pp. 1213-1220 ◽  
Author(s):  
Thomas Considine ◽  
Albert Robbat, Jr.

2018 ◽  
Vol 41 (5) ◽  
Author(s):  
Ananias Francisco Dias Júnior ◽  
Carlos Rogério Andrade ◽  
José Otávio Brito ◽  
Simone Possedente Lira ◽  
Azarias Machado de Andrade ◽  
...  

ABSTRACT Charcoal is a widely used product for barbecue, however, its quality for said use has not been well studied. Polycyclic aromatic hydrocarbons (PAHs) are a class of carcinogenic compounds that can be present in charcoal. Thus, the objective of this study was to analyze the organic phase extracted from charcoal by organic solvents, regarding the presence of PAHs. For this, a commercial charcoal brand was acquired, collected in establishments in the city of Piracicaba, São Paulo. Complementary tests were carried out to identify the wood used in the production of charcoal, such as determination of humidity, apparent density, immediate composition, calorific value, and combustion index. The organic phase extracted from the charcoal using cyclohexane was analyzed in a gas chromatograph coupled to a mass spectrometer (GC/MS) for identification of a class of sixteen PAHs. In general, charcoal presented regular characteristics for barbecue. All PAHs analyzed were detected in the organic phase extracted from the charcoal, but the observed values were below the quantified limit determined









2019 ◽  
Vol 23 (10) ◽  
pp. 1861-1866
Author(s):  
A.A. Enuneku ◽  
B. Kubeyinje

Polycyclic aromatic hydrocarbons (PAHs) are emerging ubiquitous environmental pollutants with reported carcinogenic, mutagenic and teratogenic potentials on living organisms and humans. The objective of this study was to assess the concentrations of PAHs in agricultural soils of Tsekelewu Community and environs (Egbema Kingdom) in Warri North Local Government Area of Delta State, Nigeria impacted by gas flaring using gas chromatograph system Agilent 5890 Series 11 gas chromatograph equipped with Flame ionization detector (GC-FID). The results revealed that station 1 and 2 were fairly contaminated; with mean total PAH concentration of 236.40 μg/kg and 279.75 μg/kg respectively. Stations 3, 4, 6, 7 and 9 having mean total PAH concentration of 692.45μg/kg, 726.22 μg/kg, 739.82 μg/kg, 609.38 μg/kg, and 772.99 μg/kg were moderately contaminated. Heavy contamination was recorded in station 5 and station 8 with mean PAH concentrations of 1231.08μg/kg and 1224.33 μg/kg. The dominant PAHs in soil samples were benzo(a)anthracene, phananthrene and chrysene with benzo(a)anthracene having the highest concentration across all sample stations. The PAH concentration observed in this study is thus a serious cause for concern since soil contamination from gas flaring will likely continue. Measures that will attenuate PAHs concentrations in soil should be adopted as farmers are likely exposed by largely inhalation.Keywords: Hydrocarbons; Contamination; Agricultural soils; Gas flaring 



2007 ◽  
Vol 263 (2-3) ◽  
pp. 152-170 ◽  
Author(s):  
Katja Dzepina ◽  
Janet Arey ◽  
Linsey C. Marr ◽  
Douglas R. Worsnop ◽  
Dara Salcedo ◽  
...  


2005 ◽  
Vol 34 (5) ◽  
pp. 1755-1762 ◽  
Author(s):  
Thomas Spriggs ◽  
M. Katherine Banks ◽  
Paul Schwab


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