Transition-metal complexes of a binucleating clathrochelate ligand: a reinvestigation of the crystal structure

The synthesis and structural characterization of a square-planar copper(II) complex with pyridoxal S-methylisothiosemicarbazone (PLITSC) of the formula [Cu(PLITSC?H)H2O]Br?H2O (1) as the first Cu(II) complex with monoanionic form of this ligand were described. Complex 1 together with two previously synthesized complexes [Cu(PLITSC)Br2] (2) and [Cu(PLITSC)Br(MeOH)]Br (3) were characterized by elemental analysis, IR and electronic spectra and also by the methods of thermal analysis, conductometry and magnetochemistry.

Download Full-text

ChemInform Abstract: Aminosilanes in Organic Synthesis. Preparation of New Expanded Porphyrin Ligands and Bimetallic Transition-Metal Complexes. Crystal Structure of a Tetrapyrrole Macrocycle Dirhodium Complex.

ChemInform ◽

10.1002/chin.199345188 ◽

2010 ◽

Vol 24 (45) ◽

pp. no-no

Author(s):

F. H. CARRE ◽

R. J. P. CORRIU ◽

G. BOLIN ◽

J. J. E. MOREAU ◽

C. VERNHET

Keyword(s):

Crystal Structure ◽

Transition Metal ◽

Metal Complexes ◽

Organic Synthesis ◽

Transition Metal Complexes ◽

Tetrapyrrole Macrocycle ◽

Expanded Porphyrin

Download Full-text

Transition-metal complexes of a binucleating clathrochelate ligand: a reinvestigation of the crystal structure

Transition metal complexes with Girard reagent-based ligands, Part I: Synthesis and crystal structure of the first cobalt(III) complexes with Schiff base derivative of Girard reagent

Transition-Metal Complexes of the Optically Active Cyclopentadienyl Ligand PinCp*: Crystal Structure of (SRe)-(η5-PinCp*)Re(NO)(PPh3)[CONHCH(CH3)C10H7]

Transition metal complexes of the schiff bases derived from S-alkyldithiocarbazate with 2-pyridinecarboxaldehyde N-oxide—II. Syntheses, properties and X-ray crystal structure of five-coordinate copper(II) complexes

Transition metal complexes with monodeprotonated isoorotic and 2-thioisoorotic acids: Crystal structure, spectral and magnetic study, and antimicrobial activity

Synthesis, crystal structure, hydrogen bonding and spectroscopy of transition-metal complexes with the ligand (N,N′-bis(2-pyridylmethyl)-1,3-propanediamine)

ChemInform Abstract: SULFUR LIGAND-TRANSITION METAL COMPLEXES. 4. DINUCLEAR MERCAPTO COMPLEXES OF IRON(II) WITH THE TRIDENTATE LIGAND BIS(2-(DIPHENYLPHOSPHINO)ETHYL)PHENYLPHOSPHINE: SYNTHESIS AND X-RAY CRYSTAL STRUCTURE

ChemInform Abstract: Complexes of Ligands Providing Endogenous Bridges. Part 3. Non-Transition Metal Complexes of Macrocycles Derived from 2,6-Diacetyl-4-methylphenol; the Crystal Structure of a Mononuclear Barium Complex.

Synthesis, spectroscopic studies, thermal analyses, biological activity of tridentate-coordinated transition-metal complexes [M(L)X2] and crystal structure of [ZnBr2(2,6-bis(tert-butylthiomethyl)pyridine)]

Transition metal complexes with thiosemicarbazide-based ligands. Part 60. Reactions of copper(II) bromide with pyridoxal S-methylisothiosemicarbazone (PLITSC). Crystal structure of [Cu(PLITSC−H)H2O]Br•H2O

ChemInform Abstract: Aminosilanes in Organic Synthesis. Preparation of New Expanded Porphyrin Ligands and Bimetallic Transition-Metal Complexes. Crystal Structure of a Tetrapyrrole Macrocycle Dirhodium Complex.

Transition-Metal Complexes of the Optically Active Cyclopentadienyl Ligand PinCp: Crystal Structure of (SRe)-(η5-PinCp)Re(NO)(PPh3)[CONHCH(CH3)C10H7]