Electronic structure factors of silicon-hydrogen bond activation by transition metals. Valence photoelectron spectra of (.eta.5-C5H4CH3)Mn(CO)(PMe3)HSiCl3 and (.eta.5-C5H4CH3)Mn(CO)(PMe3)HSiHPh2 (Me = CH3, Ph = C6H5)

Dennis L. Lichtenberger; Anjana Rai-Chaudhuri

doi:10.1021/ic00330a015

Electronic structure factors of silicon-hydrogen bond activation by transition metals. Valence photoelectron spectra of (.eta.5-C5H4CH3)Mn(CO)(PMe3)HSiCl3 and (.eta.5-C5H4CH3)Mn(CO)(PMe3)HSiHPh2 (Me = CH3, Ph = C6H5)

Inorganic Chemistry ◽

10.1021/ic00330a015 ◽

1990 ◽

Vol 29 (5) ◽

pp. 975-981 ◽

Cited By ~ 15

Author(s):

Dennis L. Lichtenberger ◽

Anjana Rai-Chaudhuri

Keyword(s):

Hydrogen Bond ◽

Electronic Structure ◽

Transition Metals ◽

Bond Activation ◽

Photoelectron Spectra ◽

Structure Factors

Electronic structure factors of Ge–H bond activation by transition metals. Photoelectron spectra of [Mn(η5-C5H5)(CO)2(HGePh3)], [Mn(η5-C5H4Me)(CO)2(HGePh3)], and [Mn(η5-C5Me5)(CO)2(HGePh3)]

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9900002161 ◽

1990 ◽

pp. 2161-2166 ◽

Cited By ~ 4

Author(s):

Dennis L. Lichtenberger ◽

Anjana Rai-Chaudhuri

Keyword(s):

Electronic Structure ◽

Transition Metals ◽

Bond Activation ◽

Photoelectron Spectra ◽

Structure Factors

Electronic structure factors of silicon-hydrogen bond activation by transition metals. The valence photoelectron spectrum of silylmanganese complex (.eta.5-C5H5)Mn(CO)2HSiCl3

Journal of the American Chemical Society ◽

10.1021/ja00192a015 ◽

1989 ◽

Vol 111 (10) ◽

pp. 3583-3591 ◽

Cited By ~ 21

Author(s):

Dennis L. Lichtenberger ◽

Anjana Rai-Chaudhuri

Keyword(s):

Hydrogen Bond ◽

Electronic Structure ◽

Transition Metals ◽

Photoelectron Spectrum ◽

Bond Activation ◽

Structure Factors

Electronic structure control of silicon-hydrogen bond activation by transition metals. 2. Valence photoelectron spectra of (.eta.5-C5H4CH3)Mn(CO)2HSiPh3, (.eta.5-C5H4CH3)Mn(CO)2HSiHPh2 and (.eta.5-C5H4CH3)Mn(CO)2HSiFPh2 (Ph = C6H5)

Journal of the American Chemical Society ◽

10.1021/ja00163a004 ◽

1990 ◽

Vol 112 (7) ◽

pp. 2492-2497 ◽

Cited By ~ 19

Author(s):

Dennis L. Lichtenberger ◽

Anjana Rai-Chaudhuri

Keyword(s):

Hydrogen Bond ◽

Electronic Structure ◽

Transition Metals ◽

Bond Activation ◽

Photoelectron Spectra ◽

Structure Control

ChemInform Abstract: Electronic Structure Factors of Si-H Bond Activation by Transition Metals. The Valence Photoelectron Spectrum of (η5-C5H5)Mn(CO)2HSiCl3.

ChemInform ◽

10.1002/chin.198933060 ◽

1989 ◽

Vol 20 (33) ◽

Author(s):

D. L. LICHTENBERGER ◽

A. RAI-CHAUDHURI

Keyword(s):

Electronic Structure ◽

Transition Metals ◽

Photoelectron Spectrum ◽

Bond Activation ◽

Structure Factors

ChemInform Abstract: Electronic Structure Control of Si-H Bond Activation by Transition Metals. Part 2. Valence Photoelectron Spectra of (η5-C5H4CH3)Mn(CO)2HSiPh3, (η5-C5H4CH3)Mn(CO)2HSiHPh2, and (η5-C5H4CH3)Mn(CO)2HSiFPh2 (Ph: C6H5).

ChemInform ◽

10.1002/chin.199029035 ◽

1990 ◽

Vol 21 (29) ◽

Author(s):

D. L. LICHTENBERGER ◽

A. RAI-CHAUDHURI

Keyword(s):

Electronic Structure ◽

Transition Metals ◽

Bond Activation ◽

Photoelectron Spectra ◽

Structure Control

Additions and Corrections. Electronic Structure Factors of Carbon-Hydrogen Bond Activation. The Photoelectron Spectroscopy of (Cyclohexenyl) manganese Tricarbonyl

Journal of the American Chemical Society ◽

10.1021/ja00282a602 ◽

1986 ◽

Vol 108 (22) ◽

pp. 7134-7134

Author(s):

Dennis L. Lichtenberger ◽

Glen E. Kellogg

Keyword(s):

Hydrogen Bond ◽

Electronic Structure ◽

Photoelectron Spectroscopy ◽

Bond Activation ◽

Structure Factors ◽

Carbon Hydrogen Bond Activation ◽

Manganese Tricarbonyl

ChemInform Abstract: Electronic Structure Factors of Carbon - Hydrogen Bond Activation. The Photoelectron Spectroscopy of (Cyclohexenyl)manganese Tricarbonyl.

Chemischer Informationsdienst ◽

10.1002/chin.198637067 ◽

1986 ◽

Vol 17 (37) ◽

Author(s):

D. L. LICHTENBERGER ◽

G. E. KELLOGG

Keyword(s):

Hydrogen Bond ◽

Electronic Structure ◽

Photoelectron Spectroscopy ◽

Bond Activation ◽

Structure Factors ◽

Carbon Hydrogen Bond Activation ◽

Manganese Tricarbonyl

Electronic structure factors of carbon-hydrogen bond activation. The photoelectron spectroscopy of (cyclohexenyl)manganese tricarbonyl

Journal of the American Chemical Society ◽

10.1021/ja00270a012 ◽

1986 ◽

Vol 108 (10) ◽

pp. 2560-2567 ◽

Cited By ~ 16

Author(s):

Dennis L. Lichtenberger ◽

Glen Eugene. Kellogg

Keyword(s):

Hydrogen Bond ◽

Electronic Structure ◽

Photoelectron Spectroscopy ◽

Bond Activation ◽

Structure Factors ◽

Carbon Hydrogen Bond Activation ◽

Manganese Tricarbonyl

The molecular and electronic structure of carbon–hydrogen bond activation and transition metal assisted hydrogen transfer

Coordination Chemistry Reviews ◽

10.1016/j.ccr.2008.07.015 ◽

2009 ◽

Vol 253 (7-8) ◽

pp. 1202-1218 ◽

Cited By ~ 64

Author(s):

Benjamin Alan Vastine ◽

Michael B. Hall

Keyword(s):

Hydrogen Bond ◽

Electronic Structure ◽

Transition Metal ◽

Hydrogen Transfer ◽

Bond Activation ◽

Carbon Hydrogen Bond Activation ◽

Molecular And Electronic Structure

The He(I) and He(II) Photoelectron Spectra of Tm2Zn (Tm = (C5H5)Fe(CO)2, (C5H5)M(CO)3; M = Cr, Mo, W)

Zeitschrift für Naturforschung B ◽

10.1515/znb-1984-0909 ◽

1984 ◽

Vol 39 (9) ◽

pp. 1206-1210

Author(s):

Jaap N. Louwen ◽

Derk J. Stufkens ◽

Ad Oskam

Keyword(s):

Electronic Structure ◽

Transition Metals ◽

Ionization Energy ◽

Photoelectron Spectra ◽

Metal Bond ◽

Metal Metal

UV photoelectron spectra of the title compounds are reported. Assignments are made with the help of He(I)/He(II) intensity differences, shift effects upon substitution and comparison with related molecules. Previously drawn conclusions about the electronic structure of similar complexes also hold for the compounds. It is indicated that the ionization energy for the symmetric metal-metal bond strongly depends on the overlap between transition and post-transition metals.