Synthesis, Characterization, and Electrochemical Relationships of Dinuclear Complexes of Platinum(II) and Platinum(III) Containing Ortho-Metalated Tertiary Arsine Ligands

2004 ◽  
Vol 43 (24) ◽  
pp. 7752-7763 ◽  
Author(s):  
Martin A. Bennett ◽  
Suresh K. Bhargava ◽  
Alan M. Bond ◽  
Alison J. Edwards ◽  
Si-Xuan Guo ◽  
...  
Keyword(s):  
Dinuclear Complexes ◽  
Tertiary Arsine

DV-Xα calculations on some metallacyclopentadienyl dinuclear complexes

1989 ◽  
Vol 86 ◽  
pp. 841-846 ◽  
Author(s):  
Maurizio Casarin ◽  
Gaetano Granozzi
Keyword(s):  
Dinuclear Complexes

Synthesis, Structural Features, Absorption Spectra, Redox Behaviour and Luminescence Properties of Ruthenium(II) Rack-Type Dinuclear Complexes with Ditopic, Hydrazone-Based Ligands

2005 ◽  
Vol 11 (13) ◽  
pp. 3997-4009 ◽  
Author(s):  
Adrian-Mihail Stadler ◽  
Fausto Puntoriero ◽  
Sebastiano Campagna ◽  
Nathalie Kyritsakas ◽  
Richard Welter ◽  
...  
Keyword(s):  
Absorption Spectra ◽  
Structural Features ◽  
Luminescence Properties ◽  
Dinuclear Complexes ◽  
Redox Behaviour

Reactivity of an Arene Cobalt Triple Decker Complex Towards Various Ligands. Facile Arene Displacement in [Bis{( η5-pentamethylcyclopentadienyl)cobalt}-μ-{η4: η4-toluene}]

1995 ◽  
Vol 50 (7) ◽  
pp. 1055-1060 ◽  
Author(s):  
Jörg J. Schneider
Keyword(s):  
Room Temperature ◽  
Elemental Sulfur ◽  
Organic Ligands ◽  
Dinuclear Complexes ◽  
Sulfide Cluster

The triple decker complex [{(η5-Cp*)Co}2-μ-{η4: η4-toluene}] 1b exhibits an unusual reactivity towards a variety of organic ligands, 1b reacts with CO, ethene, butadiene, H2, Al2O3, hexafluorobenzene, 1.5 Cod, 2-butyne, phenanthrene, naphthalene and the dinuclear Ni cluster [{(η5-Cp)NiP(C2H5)3}2] to form mainly mononuclear organocobalt complexes. Reaction of 1b with NO and the diazoalkanes di-t-butyl-diazomethane and 2-diazo-1,1′,3,3′-tetramethylcyclohexane results in the formation of the dinuclear complexes [{(η5-Cp*)CoNO}2], [{(η5-Cp*)(di-t-butyl-diazomethane)Co}2] and [{(η5-Cp*)(2-diazo-1,1′,3,3′-tetramethylcyclohexane) Co}2], respectively. In the reaction of 1b with elemental sulfur the formation of a tetranuclear Co-sulfide cluster is observed. In the majority of the reactions studied, l b looses its toluene ligand already at room temperature indicating an unusual high and hitherto unprecedented reactivity of an arene triple decker complex.

Comparative Study of Mono- and Dinuclear Complexes of Late 3d-Metal Chlorides withN,N-Dimethylformamide in the Gas phase†

2011 ◽  
Vol 50 (3) ◽  
pp. 771-782 ◽  
Author(s):  
Lucie Ducháčková ◽  
Jana Roithová ◽  
Petr Milko ◽  
Jan Žabka ◽  
Nikos Tsierkezos ◽  
...  
Keyword(s):  
Comparative Study ◽  
Gas Phase ◽  
Dinuclear Complexes ◽  
Metal Chlorides
Sign in / Sign up

Export Citation Format

Share Document