Dimethylaminoborane (H2BNMe2) Coordination to Late Transition Metal Centers: Snapshots of the B–H Oxidative Addition Process.

2011 ◽  
Vol 50 (21) ◽  
pp. 11039-11045 ◽  
Author(s):  
Gaëtan Bénac-Lestrille ◽  
Ulrike Helmstedt ◽  
Laure Vendier ◽  
Gilles Alcaraz ◽  
Eric Clot ◽  
...  
Keyword(s):  
Transition Metal ◽  
Oxidative Addition ◽  
Late Transition Metal ◽  
Metal Centers ◽  
Late Transition

Factors Promoting Alkene Migratory Insertion into Metal-Nitrogen Bond during Hydroamination in Recent Studies

2021 ◽  
Vol 18 ◽  
Author(s):  
Wenlai Han
Keyword(s):  
Transition Metal ◽  
Late Transition Metal ◽  
Electronic Effects ◽  
Metal Centers ◽  
Unsaturated Bond ◽  
Factors Influencing ◽  
Migratory Insertion ◽  
Late Transition ◽  
Metal Catalyzed ◽  
Nitrogen Bond

: Migratory insertion is a fundamental organometallic transformation that enables the functionalization of an unsaturated bond. Recent reports on catalytic hydroamination provide evidence that supports an intermolecular migratory insertion pathway featuring alkene insertion into metal-nitrogen (M-N) bonds. This article presents factors influencing the rate of migratory insertion in late-transition metal-catalyzed hydroamination, including steric and electronic effects from ligands, alkenes, and metal centers, along with stabilization from coordinated amine intermediates and ordered transition states.

Reactivity of Dinitrogen Bound to Mid- and Late-Transition-Metal Centers

2015 ◽  
Vol 2015 (4) ◽  
pp. 567-598 ◽  
Author(s):  
Nitesh Khoenkhoen ◽  
Bas de Bruin ◽  
Joost N. H. Reek ◽  
Wojciech I. Dzik
Keyword(s):  
Transition Metal ◽  
Late Transition Metal ◽  
Metal Centers ◽  
Late Transition

scholarly journals Reactivity of Dinitrogen Bound to Mid- and Late-Transition-Metal Centers

2015 ◽  
Vol 2015 (4) ◽  
pp. 554-554
Author(s):  
Nitesh Khoenkhoen ◽  
Bas de Bruin ◽  
Joost N. H. Reek ◽  
Wojciech I. Dzik
Keyword(s):  
Transition Metal ◽  
Late Transition Metal ◽  
Metal Centers ◽  
Late Transition

The σ-CAM Mechanism: σ Complexes as the Basis of σ-Bond Metathesis at Late-Transition-Metal Centers

ChemInform ◽  
2007 ◽  
Vol 38 (26) ◽  
Author(s):  
Robin N. Perutz ◽  
Sylviane Sabo-Etienne
Keyword(s):  
Transition Metal ◽  
Late Transition Metal ◽  
Metal Centers ◽  
Cam Mechanism ◽  
Late Transition

The σ-CAM Mechanism: σ Complexes as the Basis of σ-Bond Metathesis at Late-Transition-Metal Centers

2007 ◽  
Vol 46 (15) ◽  
pp. 2578-2592 ◽  
Author(s):  
Robin N. Perutz ◽  
Sylviane Sabo-Etienne
Keyword(s):  
Transition Metal ◽  
Late Transition Metal ◽  
Metal Centers ◽  
Cam Mechanism ◽  
Late Transition

scholarly journals Reactivity of Dinitrogen Bound to Mid- and Late-Transition-Metal Centers (Eur. J. Inorg. Chem. 4/2015)

2015 ◽  
Vol 2015 (4) ◽  
pp. n/a-n/a
Author(s):  
Nitesh Khoenkhoen ◽  
Bas de Bruin ◽  
Joost N. H. Reek ◽  
Wojciech I. Dzik
Keyword(s):  
Transition Metal ◽  
Late Transition Metal ◽  
Metal Centers ◽  
Late Transition
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