Factors Promoting Alkene Migratory Insertion into Metal-Nitrogen Bond during Hydroamination in Recent Studies
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: Migratory insertion is a fundamental organometallic transformation that enables the functionalization of an unsaturated bond. Recent reports on catalytic hydroamination provide evidence that supports an intermolecular migratory insertion pathway featuring alkene insertion into metal-nitrogen (M-N) bonds. This article presents factors influencing the rate of migratory insertion in late-transition metal-catalyzed hydroamination, including steric and electronic effects from ligands, alkenes, and metal centers, along with stabilization from coordinated amine intermediates and ordered transition states.
2011 ◽
Vol 255
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pp. 1440-1459
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2015 ◽
Vol 2015
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pp. 567-598
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2015 ◽
Vol 2015
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pp. 554-554
2007 ◽
Vol 65
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pp. 717-723
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2012 ◽
Vol 8
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pp. 3119-3127
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