Synthesis and Characterization of the Trihalophosphine Compounds of Ruthenium [RuX2(η6-cymene)(PY3)] (X = Cl, Br, Y = F, Cl, Br) and the Related PF2(NMe2) and P(NMe2)3Compounds; Multinuclear NMR Spectroscopy and the X-ray Single Crystal Structures of [RuBr2(η6-cymene)(PF3)], [RuBr2(η6-cymene)(PF2{NMe2})], and [RuI2(η6-cymene)(P{NMe2}3)]

2008 ◽  
Vol 47 (20) ◽  
pp. 9279-9292 ◽  
Author(s):  
Ahmed M. A. Boshaala ◽  
Stephen J. Simpson ◽  
Jochen Autschbach ◽  
Shaohui Zheng
Keyword(s):  
Nmr Spectroscopy ◽  
Single Crystal ◽  
Crystal Structures ◽  
Synthesis And Characterization ◽  
X Ray ◽  
Multinuclear Nmr ◽  
Single Crystal Structures ◽  
Multinuclear Nmr Spectroscopy

Synthesis and characterization of cis and trans isomers of [NiL2(NCS)2] [L=1-(2-aminoethyl)pyrrolidine]: X-ray single-crystal structures

Polyhedron ◽  
2000 ◽  
Vol 19 (15) ◽  
pp. 1803-1807 ◽  
Author(s):  
Inamur Rahaman Laskar ◽  
Tapas Kumar Maji ◽  
Siddhartha Chaudhuri ◽  
Ashutosh Ghosh ◽  
Nirmalendu Ray Chaudhuri
Keyword(s):  
Single Crystal ◽  
Crystal Structures ◽  
Synthesis And Characterization ◽  
Trans Isomers ◽  
X Ray ◽  
Single Crystal Structures ◽  
Cis And Trans Isomers ◽  
Cis And Trans

Anionic indabenzene: synthesis and characterization

2017 ◽  
Vol 53 (99) ◽  
pp. 13260-13263 ◽  
Author(s):  
Taichi Nakamura ◽  
Katsunori Suzuki ◽  
Makoto Yamashita
Keyword(s):  
Nmr Spectroscopy ◽  
Synthesis And Characterization ◽  
X Ray ◽  
Multinuclear Nmr ◽  
X Ray Crystallography ◽  
Multinuclear Nmr Spectroscopy

An anionic indabenzene was synthesized via the transmetallation of an aluminacyclohexadiene with bulky silyl substituents, and fully characterized using multinuclear NMR spectroscopy and X-ray crystallography.

Synthesis and Characterization of the nido-Platinaborane 7,7-(PPh3)2-7-PtB10H11-11-OC(O)Me

2011 ◽  
Vol 66 (4) ◽  
pp. 387-391
Author(s):  
Jinling Miao ◽  
Yong Nie ◽  
Haiyan Chen ◽  
Daqi Wang ◽  
Markus Enders ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Hydrogen Bonds ◽  
Single Crystal ◽  
Elemental Analysis ◽  
Chain Structure ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ir And Nmr Spectroscopy

The reaction of closo-B10H102− with PtCl2(PPh3)2 in the presence of MeCOSH afforded the title platinaborane nido-7,7-(PPh3)2-7-PtB10H11-11-OC(O)Me (1), which has been characterized by IR and NMR spectroscopy, MS, elemental analysis, and single-crystal X-ray diffraction. In contrast to the known products having exo-polyhedral Pt-S-C-O-B ring(s) from the same reaction with Ph- COSH, compound 1 has a B-acetoxy group on the open PtB4 face of the nido-PtB10 cluster. The structure of 1 features both intramolecular/intermolecular C-H· · ·O hydrogen bonds and intramolecular C-H· · ·H-B dihydrogen bonds, which link the molecules into a 1-D chain structure.

scholarly journals Ring opening polymerisation of L and rac lactide using group 4 permethylpentalene aryloxides and alkoxides

2021 ◽  
Author(s):  
Zoe Turner ◽  
Jessica Lamb ◽  
Thomas Robinson ◽  
Dipa Mandal ◽  
Jean-Charles Buffet ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Single Crystal ◽  
Ring Opening ◽  
X Ray Diffraction ◽  
X Ray ◽  
Multinuclear Nmr ◽  
New Family ◽  
Group 4 ◽  
Multinuclear Nmr Spectroscopy

A new family of group 4 permethylpentalene (C8Me62–; Pn*) aryloxide and alkoxide complexes have been synthesised and fully characterised by multinuclear NMR spectroscopy and single-crystal X-ray diffraction; (η8-C8Me6)Zr(OR)2 (R =...

Synthesis and Reactivity of Novel Alkali Metal Stannides

2004 ◽  
Vol 59 (11-12) ◽  
pp. 1462-1470 ◽  
Author(s):  
Thorsten Schollmeier ◽  
Ulrich Englich ◽  
Roland Fischer ◽  
Ingo Prass ◽  
Karin Ruhlandt ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Alkali Metal ◽  
Synthesis And Characterization ◽  
Metal Compounds ◽  
X Ray ◽  
X Ray Crystallography ◽  
Multinuclear Nmr Spectroscopy ◽  
Alkali Metal Compounds ◽  
Potassium Hydride

Reactivity and side products of reactions of diorganodihydridostannanes (R2SnH2, R = Me, nBu, tBu)) with various alkali metal compounds have been discussed. Alternatively, the synthesis and characterization of a family of novel potassium stannides are described as well. The compounds of type (RR’2Si)R”2SnK (R, R’= Me, Ph; R”= , Me, tBu, Ph) 4 - 9 were synthesized by reaction of potassium hydride with bis(silyl)stannides ((RR’2Si)2SnR”2). All compounds were characterized by multinuclear NMR spectroscopy. In addition, the tri-tert-butyltin compound 3 (LiSntBu3) and the unsymmetrical silyl substituted stannane 10 were characterized by X-ray crystallography.

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