The Lowest-Energy Ligand to Metal Charge-Transfer Absorption Band oftrans-[OsO2(Malonate)2]2-

2000 ◽  
Vol 39 (10) ◽  
pp. 2152-2155 ◽  
Author(s):  
Sandrine Stanislas ◽  
André L. Beauchamp ◽  
Christian Reber
Keyword(s):  
Charge Transfer ◽  
Absorption Band ◽  
Metal Charge ◽  
Charge Transfer Absorption Band ◽  
Metal Charge Transfer

Photochemistry of Aqueous Tetrathioantimonate(V)

1995 ◽  
Vol 50 (8) ◽  
pp. 1155-1157 ◽  
Author(s):  
H. Kunkely ◽  
A. Vogler
Keyword(s):  
Charge Transfer ◽  
Absorption Band ◽  
Electronic Spectrum ◽  
Redox Reaction ◽  
Elemental Sulfur ◽  
Metal Charge ◽  
Metal Charge Transfer

The electronic spectrum of [SbS4]3- in 10-3 M NaOH displays an absorption band at λmax = 285 nm which is assigned to a ligand-to-metal charge transfer (LMCT) transition. Upon LMCT excitation [SbS4]3- undergoes an intramolecular redox reaction with the formation of [SbS3]3- and elemental sulfur (φ = 0.11 at λirr = 333 nm).

Tuning metal to metal charge transfer properties in cyanidometal-bridged complexes by changing the auxiliary ligand on the bridge

2021 ◽  
Author(s):  
Qing-Dou Xu ◽  
Chen Zeng ◽  
Shao-Dong Su ◽  
Yu-Ying Yang ◽  
Sheng-Min Hu ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Auxiliary Ligand ◽  
Metal Charge ◽  
Transfer Properties ◽  
Metal Charge Transfer

This work shows that the energy of MMCT in cyanidometal-bridged complexes can be tuned systematically by changing the auxiliary ligand of the cyanidometal bridge.

The fluorescence properties of tiara like structural thiolated palladium clusters

2017 ◽  
Vol 46 (38) ◽  
pp. 12964-12970 ◽  
Author(s):  
Jishi Chen ◽  
Yanze Pan ◽  
Zonghua Wang ◽  
Peng Zhao
Keyword(s):  
Charge Transfer ◽  
Fluorescence Properties ◽  
Metal Charge ◽  
Palladium Clusters ◽  
Metal Charge Transfer

A series of tiara like structural Pdn(SR)2n (5 ≤ n ≤ 20) nanoclusters exhibit emission at 620 nm with excitation at around 268 nm. Their emission is due to ligand to metal charge transfer.

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