Integrated Selective Catalytic Reduction–Diesel Particulate Filter Aftertreatment: Insights into Pressure Drop, NOx Conversion, and Passive Soot Oxidation Behavior

2014 ◽  
Vol 53 (45) ◽  
pp. 17547-17557 ◽  
Author(s):  
Kenneth G. Rappé
Keyword(s):  
Pressure Drop ◽  
Selective Catalytic Reduction ◽  
Diesel Particulate Filter ◽  
Oxidation Behavior ◽  
Catalytic Reduction ◽  
Soot Oxidation ◽  
Particulate Filter ◽  
Diesel Particulate ◽  
Nox Conversion

Comparative analysis on the effects of diesel particulate filter and selective catalytic reduction systems on a wide spectrum of chemical species emissions

2018 ◽  
Author(s):  
Z. Gerald Liu ◽  
Devin R. Berg ◽  
Thaddeus A. Swor ◽  
James J. Schauer‡
Keyword(s):  
Diesel Engine ◽  
Selective Catalytic Reduction ◽  
Diesel Particulate Filter ◽  
Catalytic Reduction ◽  
Wide Spectrum ◽  
Chemical Species ◽  
Pollutant Emissions ◽  
Particulate Filter ◽  
Diesel Particulate ◽  
Aftertreatment Systems

Two methods, diesel particulate filter (DPF) and selective catalytic reduction (SCR) systems, for controlling diesel emissions have become widely used, either independently or together, for meeting increasingly stringent emissions regulations world-wide. Each of these systems is designed for the reduction of primary pollutant emissions including particulate matter (PM) for the DPF and nitrogen oxides (NOx) for the SCR. However, there have been growing concerns regarding the secondary reactions that these aftertreatment systems may promote involving unregulated species emissions. This study was performed to gain an understanding of the effects that these aftertreatment systems may have on the emission levels of a wide spectrum of chemical species found in diesel engine exhaust. Samples were extracted using a source dilution sampling system designed to collect exhaust samples representative of real-world emissions. Testing was conducted on a heavy-duty diesel engine with no aftertreatment devices to establish a baseline measurement and also on the same engine equipped first with a DPF system and then a SCR system. Each of the samples was analyzed for a wide variety of chemical species, including elemental and organic carbon, metals, ions, n-alkanes, aldehydes, and polycyclic aromatic hydrocarbons, in addition to the primary pollutants, due to the potential risks they pose to the environment and public health. The results show that the DPF and SCR systems were capable of substantially reducing PM and NOx emissions, respectively. Further, each of the systems significantly reduced the emission levels of the unregulated chemical species, while the notable formation of new chemical species was not observed. It is expected that a combination of the two systems in some future engine applications would reduce both primary and secondary emissions significantly.

Evaluation of Real-World Gaseous Emissions Performance of Selective Catalytic Reduction and Diesel Particulate Filter Bus Retrofits

2019 ◽  
Vol 53 (8) ◽  
pp. 4440-4449 ◽  
Author(s):  
Robin Smit ◽  
Christos Keramydas ◽  
Leonidas Ntziachristos ◽  
Ting-shek Lo ◽  
Kwok-lam Ng ◽  
...  
Keyword(s):  
Selective Catalytic Reduction ◽  
Real World ◽  
Diesel Particulate Filter ◽  
Catalytic Reduction ◽  
Particulate Filter ◽  
Gaseous Emissions ◽  
Diesel Particulate

scholarly journals Nanostructure changes in diesel soot during NO2–O2 oxidation under diesel particulate filter-like conditions toward filter regeneration

2018 ◽  
Vol 20 (8-9) ◽  
pp. 953-966 ◽  
Author(s):  
Madhu Singh ◽  
Mek Srilomsak ◽  
Yujun Wang ◽  
Katsunori Hanamura ◽  
Randy Vander Wal
Keyword(s):  
Diesel Particulate Filter ◽  
Surface Oxidation ◽  
Soot Oxidation ◽  
Diesel Soot ◽  
Particulate Filter ◽  
Exhaust Gas ◽  
Fringe Analysis ◽  
Diesel Particulate ◽  
Oxidation Rates ◽  
Passive Regeneration

Development of the regeneration process on diesel particulate filters requires a better understanding of soot oxidation phenomena, especially its relation to soot nanostructure. Nitrogen dioxide (NO2) is known to play an essential role in passive regeneration by oxidizing soot at low temperatures, especially in the presence of oxygen (O2) in the exhaust. However, change in soot nanostructure due to oxidation by NO2–O2 mixtures has not received much attention. This work focuses on nanostructure evolution during passive regeneration of the diesel particulate filter by oxidation of soot at normal exhaust gas temperatures (300°C–400°C). High-resolution transmission electron microscopy of partially oxidized model carbons (R250, M1300, arc-generated soot) and diesel soot under NO2–O2 mixtures is used to investigate physical changes in nanostructure correlating with the material’s behavior during oxidation. Microscopy reveals the changing nanostructure of model carbons during oxidation while fringe analysis of the images points to the differences in the structural metrics of fringe length and tortuosity of the resultant structures. The variation in oxidation rates highlights the inter-dependence of the material’s reactivity with its structure. NO2 preferentially oxidizes edge-site carbon, promotes surface oxidation by altering the particle’s burning mode with increased overall reactivity of NO2+O2 resulting in inhibition of internal burning, typically observed by O2 at exhaust gas temperatures.

Experimental study of lubricant-derived ash effects on diesel particulate filter performance

2019 ◽  
pp. 146808741987457 ◽  
Author(s):  
Jun Zhang ◽  
Yanfei Li ◽  
Victor W Wong ◽  
Shijin Shuai ◽  
Jinzhu Qi ◽  
...  
Keyword(s):  
Pressure Drop ◽  
Diesel Particulate Filter ◽  
Particulate Filter ◽  
Maximum Temperature ◽  
Particle Emissions ◽  
Diesel Particulate ◽  
Particulate Filters ◽  
Filter Performance ◽  
Soot Loading ◽  
Active Regeneration

Diesel particulate filters are indispensable for diesel engines to meet the increasingly stringent emission regulations. A large amount of ash would accumulate in the diesel particulate filter over time, which would significantly affect the diesel particulate filter performance. In this work, the lubricant-derived ash effects on diesel particulate filter pressure drop, diesel particulate filter filtration performance, diesel particulate filter temperature field during active regeneration, and diesel particulate filter downstream emissions during active regeneration were studied on an engine test bench. The test results show that the ash accumulated in the diesel particulate filter would decrease the diesel particulate filter pressure drop due to the “membrane effect” when the diesel particulate filter ash loading is lower than about 10 g/L, beyond which the diesel particulate filter pressure drop would be increased due to the reduction of diesel particulate filter effective volume. The ash loaded in the diesel particulate filter could significantly improve the diesel particulate filter filtration efficiency because it would fill the pores of diesel particulate filter wall. The diesel particulate filter peak temperature during active regeneration is consistent with the diesel particulate filter initial actual soot loading density prior to regeneration at various diesel particulate filter ash loading levels, while the diesel particulate filter maximum temperature gradient would increase with the diesel particulate filter ash loading increase, whether the diesel particulate filter is regenerated at the same soot loading level or the same diesel particulate filter pressure drop level. The ash accumulation in the diesel particulate filter shows little effects on diesel particulate filter downstream CO, total hydrocarbons, N2O emissions, and NO2/NO x ratio during active regeneration. However, a small amount of SO2 emissions was observed when the diesel particulate filter ash loading is higher than 10 g/L. The ash accumulated in the diesel particulate filter would increase the diesel particulate filter downstream sub-23 nm particle emissions but decrease larger particle emissions during active regeneration.

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