Solvent isotope effect on orientational correlation times of the nitrate ion in dilute aqueous solution

1990 ◽  
Vol 94 (16) ◽  
pp. 6179-6183 ◽  
Author(s):  
M. Nakahara ◽  
A. Adachi ◽  
H. Kiyoyama ◽  
A. Shimizu ◽  
Y. Taniguchi ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Isotope Effect ◽  
Solvent Isotope Effect ◽  
Correlation Times ◽  
Nitrate Ion ◽  
Dilute Aqueous Solution ◽  
Solvent Isotope ◽  
Orientational Correlation

Deuterium solvent isotope effect on the basicity of methanol. Deuterium fractionation factor for CH3OL2+ in aqueous solution

1986 ◽  
Vol 90 (4) ◽  
pp. 543-545 ◽  
Author(s):  
Joseph L. Kurz ◽  
Stanley L. Hazen ◽  
Linda C. Kurz
Keyword(s):  
Aqueous Solution ◽  
Isotope Effect ◽  
Solvent Isotope Effect ◽  
Fractionation Factor ◽  
Solvent Isotope

Infrared Band Width of the Nitrate Ion v2Mode. Ionic Lifetimes and a Solvent Isotope Effect

1965 ◽  
Vol 69 (10) ◽  
pp. 3650-3652 ◽  
Author(s):  
J. C. Evans ◽  
G. Y-S. Lo
Keyword(s):  
Isotope Effect ◽  
Band Width ◽  
Solvent Isotope Effect ◽  
Infrared Band ◽  
Nitrate Ion ◽  
Solvent Isotope

Solvent isotope effect on the hydroxide-ion-catalyzed hydration of ketenes in aqueous solution

1999 ◽  
Vol 77 (4) ◽  
pp. 459-462
Author(s):  
J. Andraos ◽  
Y. Chiang ◽  
S.J. Eustace ◽  
A.J. Kresge ◽  
S.W. Paine ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Isotope Effect ◽  
Solvent Isotope Effect ◽  
Hydroxide Ion ◽  
Solvent Isotope

Kinetic solvent isotope effect studies on the methanolysis of 1-phenylethyl chlorides

1993 ◽  
Vol 6 (6) ◽  
pp. 361-366 ◽  
Author(s):  
Ikchoon Lee ◽  
Won Heui Lee ◽  
Hai Whang Lee
Keyword(s):  
Isotope Effect ◽  
Solvent Isotope Effect ◽  
Solvent Isotope

Neutral Solvolysis of Acyl Carbon and the Temperature Dependence of the Kinetic Solvent Isotope Effect

1975 ◽  
Vol 53 (6) ◽  
pp. 869-877 ◽  
Author(s):  
B. Rossall ◽  
R. E. Robertson
Keyword(s):  
Temperature Dependence ◽  
Isotope Effect ◽  
Solvent Isotope Effect ◽  
Acyl Carbon ◽  
Rate Of Hydrolysis ◽  
Solvent Isotope ◽  
Neutral Conditions ◽  
Hydrolysis Of

The temperature dependence of the rate of hydrolysis of benzoic, phthalic, and succinic anhydrides have been determined in H2O and D2O under "neutral" conditions. Corresponding data have been obtained for methyl trifluoroacetate. While both series supposedly react by the same BAc2 mechanism, remarkable differences are made obvious by this investigation. Possible sources of such differences are proposed.

Proton-coupled electron transfer between [Ru(bpy)2(py)OH2]2+ and [Ru(bpy)2(py)O]2+. A solvent isotope effect (kH2O/kD2O) of 16.1

1981 ◽  
Vol 103 (10) ◽  
pp. 2897-2899 ◽  
Author(s):  
Robert A. Binstead ◽  
Bruce A. Moyer ◽  
George J. Samuels ◽  
Thomas J. Meyer
Keyword(s):  
Electron Transfer ◽  
Isotope Effect ◽  
Solvent Isotope Effect ◽  
Proton Coupled Electron Transfer ◽  
Solvent Isotope

An Unusual Solvent Isotope Effect in the Reaction of W(CO)5(solv) (solv = Cyclohexane or Cyclohexane-d12) with THF

2000 ◽  
Vol 19 (9) ◽  
pp. 1682-1691 ◽  
Author(s):  
Riki Paur-Afshari ◽  
J. Lin ◽  
Richard H. Schultz
Keyword(s):  
Isotope Effect ◽  
Solvent Isotope Effect ◽  
Solvent Isotope

Notizen: 67Zn NMR Anomalous Solvent Isotope Effect in Aqueous Solutions

1974 ◽  
Vol 29 (4) ◽  
pp. 660-661 ◽  
Author(s):  
B. W. Epperlein ◽  
H. Krüger ◽  
. Lutz ◽  
A. Schwenk
Keyword(s):  
Aqueous Solutions ◽  
Isotope Effect ◽  
Solvent Isotope Effect ◽  
Zinc Bromide ◽  
The Difference ◽  
Solvent Isotope

For 67Zn NMR lines of solutions of ZnCl2, ZnBr2, and ZnI2 in H2O and D2O an anomalous solvent isotope effect is reported. In D2O solutions the lines are shifted to higher frequencies. The difference between the shieldings in H2O and D2O is e.g. σ(H2O) - σ(D2O) = (13.1 ±0.7) ppm for a concentration of 0.02 moles zinc bromide per mole solvent.

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