THE ELECTRICAL CONDUCTIVITY OF SOLUTIONS OF METALS IN THEIR MOLTEN HALIDES. VII. RARE EARTH METAL SYSTEMS. ELECTRON EXCHANGE BETWEEN ADJACENT OXIDATION STATES

1963 ◽  
Vol 67 (12) ◽  
pp. 2715-2717 ◽  
Author(s):  
A. S. Dworkin ◽  
H. R. Bronstein ◽  
M. A. Bredig
2018 ◽  
Vol 47 (37) ◽  
pp. 13016-13024 ◽  
Author(s):  
Sebastian Bestgen ◽  
Qien Chen ◽  
Nicholas H. Rees ◽  
Jose M. Goicoechea

The reactivity and coordination behaviour of OCP− towards three rare-earth elements: Y, Nd and Sm, was investigated. Mono- and bis-phosphaethynolate complexes in different oxidation states were prepared, leading to novel coordination modes of OCP− and ionic intermediates of Sm(ii) in the presence of 18-crown-6 or 2,2,2-crypt.


2020 ◽  
Vol 49 (42) ◽  
pp. 14985-14994
Author(s):  
Xu-Sheng Gao ◽  
Mei-Juan Ding ◽  
Jin Zhang ◽  
Li-Duo Zhao ◽  
Xiao-Ming Ren

All solid solutions (EuxY1−x-PTC, x = 0.013–0.82) are isomorphic to Eu-PTC, but different from Y-PTC, and show phase selectivity as well as excitation wavelength dependent emission.


2021 ◽  
Vol 1104 (1) ◽  
pp. 012025
Author(s):  
Sachendra ◽  
Shailesh Kumar Singh ◽  
Ujjwal ◽  
Satyajeet Kumar ◽  
Kuldeep Singh

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