Determination of the Second Dissociation Constant of Sulfuric Acid by Donnan Membrane Equilibrium1

1966 ◽  
Vol 70 (12) ◽  
pp. 3922-3927 ◽  
Author(s):  
Richard M. Wallace

1994 ◽  
Vol 23 (1) ◽  
pp. 75-80 ◽  
Author(s):  
P. Luts ◽  
J. Vanhees ◽  
J. Yperman ◽  
J. Mullens ◽  
L. C. Van Poucke






1967 ◽  
Vol 50 (5) ◽  
pp. 1102-1108
Author(s):  
Charles F Gordon ◽  
Richard J Schuckert ◽  
William E Bornak

Abstract A modified method for the determination of dithiocarbamate fungicide residues on crops is presented. A large representative subsample of the frozen crop is blended in ice-cold deaerated water and an aliquot of the homogenate is added to the analytical apparatus containing hot 5 0% sulfuric acid. Dithiocarbamates are decomposed to evolve CS2 which is removed by a continuous gentle air-sweep from the digestion flask. Variations in technique allow the analysis of dithiocarbamate fungicide residues in several ranges, 1-10, 10-200, and 200-1000 /ig maneb. Recoveries from a wide variety of crops averaged 70 to 103%. Certain crop types present low recoveries and/or high apparent control values, but modifications in the analytical procedure are successful in solving these problems.



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