Theory of Solvent Effects on Molecular Electronic Spectra. Frequency Shifts

1957 ◽  
Vol 61 (5) ◽  
pp. 562-572 ◽  
Author(s):  
E. G. McRae
Keyword(s):  
Solvent Effects ◽  
Electronic Spectra ◽  
Molecular Electronic ◽  
Frequency Shifts

A contribution to evaluation of influence of medium in electronic and infrared spectroscopy

1982 ◽  
Vol 47 (4) ◽  
pp. 1060-1068 ◽  
Author(s):  
Vojtěch Bekárek ◽  
Jan Juřina
Keyword(s):  
Refractive Index ◽  
Infrared Spectroscopy ◽  
Correlation Coefficient ◽  
Solvent Effects ◽  
Electronic Spectra ◽  
Relative Permittivity ◽  
Solvent Parameters

Dependence of ET(30) of solvent parameters on relative permittivity (ε) and refractive index (n) of solvent has been found for forty solvents in the form ET(30)=29.87 + 72.03 (ε - 1/(2ε + 1)-29.16(ε - 1) (n 2 - 1)/(2ε + 1) (2n2 + 1), the correlation coefficient being 0.958. Relation has been discussed between ET(30) and π solvent parameters and significance of the term (ε - 1). (n2 - 1)/(2ε + 1) (2n2 + 1) has been tested for evaluation of solvent effects in electronic spectra.>

Method of calculating band shape for molecular electronic spectra

1998 ◽  
Vol 19 (7) ◽  
pp. 781-796 ◽  
Author(s):  
Greg M. Pearl ◽  
M. C. Zerner ◽  
Anders Broo ◽  
John McKelvey
Keyword(s):  
Electronic Spectra ◽  
Molecular Electronic ◽  
Band Shape

Algebraic Model for Molecular Electronic Spectra

1991 ◽  
pp. 173-186 ◽  
Author(s):  
A. Frank ◽  
R. Lemus ◽  
F. Iachello
Keyword(s):  
Electronic Spectra ◽  
Algebraic Model ◽  
Molecular Electronic
Sign in / Sign up

Export Citation Format

Share Document