Exploring the Molecular Electronic Device Applications of Synthetically Versatile Silicon Pincer Complexes as Charge Transport and Electroluminescent Layers

Hexacoordinate silicon pincer complexes using 2,6-bis(benzimidizol-2-yl)pyridine (bzimpy) ligands have been developed as a multifunctional, molecular electronic materials platform. We report the synthesis, characterization, and device application of a variety of...

The experimental results of the geophysical pulse voltage generator

The paper is devoted to the development process of the geophysical pulse voltage generator. The peculiarity of the generator lies in the non-specific purpose of this type of construction. Its main function is the controlled effect on the active faults of seismically dangerous zones. The results of the field experiment with the constructed device from 2018 to 2020 are presented. During the experiments, estimations and theoretical analysis we have obtained the seismic noise recorded by means of molecular electronic instruments and determined the periods of the electrical pulses. Operational parameters of the generator were identified on the basis of experiment results. The software and hardware elements of the system were upgraded and, as a result, a new version of the geophysical pulse voltage generator was developed.

Impact of device design on the electronic and optoelectronic properties of integrated Ru-terpyridine complexes

The performance of nanoelectronic and molecular electronic devices relies strongly on the employed functional units and their addressability, which is often a matter of appropriate interfaces and device design. Here, we compare two promising designs to build up solid-state electronic devices utilizing the same functional unit. Optically addressable Ru-terpyridine complexes were incorporated in supramolecular wires or employed as ligands of gold nanoparticles and contacted by nanoelectrodes. The resulting small area nanodevices were thoroughly electrically characterized as a function of temperature and light exposure. Differences in the resulting device conductance could be attributed to the device design and the respective transport mechanism: thermally activated hopping conduction in case of Ru-terpyridine wire devices or sequential tunneling in nanoparticle-based devices. Furthermore, the conductance switching of nanoparticle-based devices upon 530 nm irradiation was attributed to plasmon-induced metal-to-ligand charge-transfer in the Ru-terpyridine complexes used as switching ligands. Finally, our results reveal a superior device performance of nanoparticle-based devices compared to molecular wire devices based on Ru-terpyridine complexes as functional units.