Surprising differences in the reactivity of cyano aromatic radical anions generated by photoinduced electron transfer

1991 ◽  
Vol 113 (1) ◽  
pp. 358-359 ◽  
Author(s):  
Matthew A. Kellett ◽  
David G. Whitten ◽  
Ian R. Gould ◽  
William R. Bergmark
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Radical Anions ◽  
Aromatic Radical

Double-Layer Effects and Distance Dependence of Electron Transfer in Reduction of Nitro Aromatic Radical Anions

Langmuir ◽  
2006 ◽  
Vol 22 (4) ◽  
pp. 1896-1902 ◽  
Author(s):  
Petra Mořkovská ◽  
Magdaléna Hromadová ◽  
Lubomír Pospíšil ◽  
Stefania Giannarelli
Keyword(s):  
Electron Transfer ◽  
Double Layer ◽  
Radical Anions ◽  
Aromatic Radical ◽  
Distance Dependence ◽  
Nitro Aromatic

Diastereoselective Protonation on Radical Anions of Electron-Deficient Alkenes via Photoinduced Electron Transfer

2004 ◽  
Vol 69 (15) ◽  
pp. 4997-5004 ◽  
Author(s):  
Tomoo Hayamizu ◽  
Hajime Maeda ◽  
Kazuhiko Mizuno
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Radical Anions

Regio- and stereoselective functionalization of electron-deficient alkenes by organosilicon compounds via photoinduced electron transfer

2003 ◽  
Vol 75 (8) ◽  
pp. 1049-1054 ◽  
Author(s):  
K. Mizuno ◽  
T. Hayamizu ◽  
Hajime Maeda
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Radical Cations ◽  
Reactive Intermediates ◽  
Radical Anions ◽  
Organosilicon Compounds ◽  
Allylic Silanes ◽  
Carbon Radicals

Regio- and stereoselective photoallylation of electron-deficient alkenes by use of allylic silanes via photoinduced electron transfer has been described. Similar photoinduced  functionalization reactions such as arylmethylation, alkylation, and silylation can be achieved by using a variety of organosilicon compounds. These photoreactions proceed via radical cations of organosilicon compounds and radical anions of electron-deficient alkenes as reactive intermediates. The key step of the photoreactions is the attack of carbon radicals, which are generated from the radical cations of organosilicon compounds, on the radical anions of alkenes. The mechanism of the regio- and stereoselective photofunctionalization is discussed.

Generation of ketyl radical anions by photoinduced electron transfer (PET) between ketones and amines. Synthetic applications

Tetrahedron ◽  
2006 ◽  
Vol 62 (27) ◽  
pp. 6459-6470 ◽  
Author(s):  
Janine Cossy ◽  
Damien Belotti
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Radical Anions ◽  
Ketyl Radical

Reactions of Aromatic Radical Anions. I. Coupling of Alkyl Free Radicals Generated by Electron Transfer to Alkyl Iodides1

1966 ◽  
Vol 88 (22) ◽  
pp. 5363-5364 ◽  
Author(s):  
G. Dann Sargent ◽  
James N. Cron ◽  
Shelton Bank
Keyword(s):  
Electron Transfer ◽  
Free Radicals ◽  
Radical Anions ◽  
Aromatic Radical

scholarly journals Competitive Electron Transfer and SN2 Reactions of Aromatic Radical Anions with Alkyl Halides and Methanesulfonates.

1998 ◽  
Vol 52 ◽  
pp. 51-61 ◽  
Author(s):  
Heidi Skovbak Sørensen ◽  
Kim Daasbjerg ◽  
Lennart Eberson ◽  
Björn Åkermark ◽  
John H. Wagenknecht ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Alkyl Halides ◽  
Radical Anions ◽  
Aromatic Radical ◽  
Sn2 Reactions
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