Passage from Concerted to Stepwise Dissociative Electron Transfer as a Function of the Molecular Structure and of the Energy of the Incoming Electron. Electrochemical Reduction of Aryldialkyl Sulfonium Cations

1994 ◽  
Vol 116 (17) ◽  
pp. 7864-7871 ◽  
Author(s):  
Claude P. Andrieux ◽  
Marc Robert ◽  
Franklin D. Saeva ◽  
J.-M. Saveant
Keyword(s):  
Molecular Structure ◽  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Dissociative Electron Transfer ◽  
Incoming Electron

Dissociative Electron Transfer to Dihaloalkanes. Electrochemical Reduction of 1,3-Dihaloadamantanes, 1,4-Dihalobicyclo[2.2.2]octanes, and 1,3-Dihalobicyclo[1.1.1]pentanes

1994 ◽  
Vol 116 (11) ◽  
pp. 4653-4659 ◽  
Author(s):  
William Adcock ◽  
Christopher I. Clark ◽  
Abdelaziz Houmam ◽  
Alexander R. Krstic ◽  
Jean Pinson ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Dissociative Electron Transfer

scholarly journals Electrochemical Reduction of G3-Factor Endoperoxide and Its Methyl Ether: Evidence for a Competition between Concerted and Stepwise Dissociative Electron Transfer

2007 ◽  
Vol 13 (4) ◽  
pp. 1174-1179 ◽  
Author(s):  
Fadia Najjar ◽  
Christiane André-Barrès ◽  
Michel Baltas ◽  
Corinne Lacaze-Dufaure ◽  
David C. Magri ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Methyl Ether ◽  
Dissociative Electron Transfer

scholarly journals RuIII(edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere versus outer-sphere mechanism

RSC Advances ◽  
2021 ◽  
Vol 11 (35) ◽  
pp. 21359-21366
Author(s):  
Debabrata Chatterjee ◽  
Marta Chrzanowska ◽  
Anna Katafias ◽  
Maria Oszajca ◽  
Rudi van Eldik
Keyword(s):  
Hydrogen Peroxide ◽  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Molecular Oxygen ◽  
Outer Sphere ◽  
Transfer Processes ◽  
Edta Complexes ◽  
Inner Sphere ◽  
Electron Transfer Processes ◽  
Sphere Mechanism

[RuII(edta)(L)]2–, where edta4– =ethylenediaminetetraacetate; L = pyrazine (pz) and H2O, can reduce molecular oxygen sequentially to hydrogen peroxide and further to water by involving both outer-sphere and inner-sphere electron transfer processes.

Crystal and Molecular Structure of Manganese(II) Lapacholate, a Novel Polymeric Species Undergoing Temperature-Reversible Metal to Ligand Electron Transfer

2009 ◽  
Vol 48 (8) ◽  
pp. 3529-3534 ◽  
Author(s):  
Francesco Caruso ◽  
Miguel A. Martínez ◽  
Miriam Rossi ◽  
Alexander Goldberg ◽  
M. Elizabeth Chacón Villalba ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Electron Transfer ◽  
Crystal And Molecular Structure ◽  
Polymeric Species

Cyclopentadienyl iron xanthate complexes. Crystal and molecular structure and electrochemical reduction of η-C5R5Fe(CO)2(η1-SC(S)OEt) (RH or CH3)

1988 ◽  
Vol 143 (1) ◽  
pp. 59-70 ◽  
Author(s):  
Moisés Morán ◽  
Isabel Cuadrado ◽  
José R. Masaguer ◽  
José Losada ◽  
Concepcion Foces-Foces ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Electrochemical Reduction ◽  
Crystal And Molecular Structure
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