Pull-push mechanism for the 1,2-hydrogen rearrangement of carbenes. Substituent and deuterium isotope effects for thermal decomposition of 1-phenyl-2-diazopropanes

1978 ◽  
Vol 100 (6) ◽  
pp. 1872-1875 ◽  
Author(s):  
Dean T. T. Su ◽  
Edward R. Thornton
Keyword(s):  
Thermal Decomposition ◽  
Isotope Effects ◽  
Deuterium Isotope Effects ◽  
Hydrogen Rearrangement

Deuterium isotope effects in the thermal decomposition of β hydroxy ketones and β-hydroxy esters

1987 ◽  
Vol 28 (31) ◽  
pp. 3555-3558 ◽  
Author(s):  
J. Quijano ◽  
M.M. Rodríguez ◽  
M. del S. Yepes ◽  
L.H. Gallego
Keyword(s):  
Thermal Decomposition ◽  
Isotope Effects ◽  
Hydroxy Ketones ◽  
Hydroxy Esters ◽  
Deuterium Isotope Effects

Secondary .alpha.-deuterium isotope effects in the thermal decomposition of 2,2'-dimethoxy-1,1'-diphenylazoethane and 1,1'-diphenylazobutane

1972 ◽  
Vol 94 (2) ◽  
pp. 539-544 ◽  
Author(s):  
Stuart E. Scheppele ◽  
William H. Rapp ◽  
Dwight W. Miller ◽  
David Wright ◽  
Terry Marriott
Keyword(s):  
Thermal Decomposition ◽  
Isotope Effects ◽  
Deuterium Isotope Effects

Mechanism of hydration and isomerisation of 4-ethylidene-2,6-di-tert-butyl-2,5-cyclohexadien-1-one. Kinetics, acid-base catalysis and solvent deuterium isotope effects

1979 ◽  
Vol 44 (1) ◽  
pp. 110-122 ◽  
Author(s):  
Jiří Velek ◽  
Bohumír Koutek ◽  
Milan Souček
Keyword(s):  
Aqueous Medium ◽  
Rate Equation ◽  
Kinetic Data ◽  
Isotope Effects ◽  
Base Catalysis ◽  
Quinone Methide ◽  
Reaction Products ◽  
Acid Base ◽  
Deuterium Isotope Effects ◽  
Hydroxybenzyl Alcohol

Competitive hydration and isomerisation of the quinone methide I at 25 °C in an aqueous medium in the region of pH 2.4-13.0 was studied spectrophotometrically. The only reaction products in the studied range of pH are 4-hydroxybenzyl alcohol (II) and 4-hydroxystyrene (III). The form of the overall rate equation corresponds to a general acid-base catalysis. The mechanism of both reactions for three markedly separated pH regions is discussed on the basis of kinetic data and solvent deuterium effect.

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