Zinc-promoted one-step joining reaction of alkyl halides, activated olefins, and carbonyl compounds

1978 ◽  
Vol 100 (13) ◽  
pp. 4314-4315 ◽  
Author(s):  
Tatsuya Shono ◽  
Ikuzo Nishiguchi ◽  
Manji Sasaki
Keyword(s):  
Carbonyl Compounds ◽  
Alkyl Halides ◽  
One Step ◽  
Activated Olefins

One-step joining reaction of thiolate anions, activated olefins, and carbonyl compounds

1979 ◽  
Vol 101 (16) ◽  
pp. 4752-4753 ◽  
Author(s):  
Tatsuya Shono ◽  
Yoshihiro Matsumura ◽  
Shigenori Kashimura ◽  
Kouhei Hatanaka
Keyword(s):  
Carbonyl Compounds ◽  
One Step ◽  
Activated Olefins ◽  
Thiolate Anions

scholarly journals Cobalt-Salen Catalyzed Electroreductive Alkylation of Activated Olefins

2019 ◽  
Vol 2019 ◽  
pp. 1-6
Author(s):  
Sylvie Condon ◽  
Céline Cannes ◽  
Fethi Bedioui
Keyword(s):  
Electrochemical Cell ◽  
Bond Formation ◽  
Iron Complex ◽  
Alkyl Halides ◽  
Sacrificial Anode ◽  
Mild Conditions ◽  
Regioselective Alkylation ◽  
Reported Study ◽  
One Step ◽  
Activated Olefins

Cobalt-Salen mediated electroreductive and regioselective alkylation of electron deficient olefins is reported in one step in an undivided electrochemical cell, in the presence of an iron rod as sacrificial anode. Although the reactivity depends on the class of alkyl halides, the reported study offers a green and expeditious electrosynthetic route for Csp3-Csp3 bond formation in mild conditions. This study also confirms the possible formation of the heterobinuclear cobalt-Salen-iron complex previously reported as the effective catalyst.

scholarly journals Copper(I) Chloride/Kieselguhr: A Versatile Catalyst for Oxidation of Alkyl Halides and Alkyl Tosylates to the Carbonyl Compounds

1999 ◽  
Vol 23 (7) ◽  
pp. 434-435
Author(s):  
Mohammed M. Hashemi ◽  
Yousef Ahmadi Beni
Keyword(s):  
Carbonyl Compounds ◽  
Alkyl Halides ◽  
Aldehydes And Ketones ◽  
High Yields

Copper(I) Chloride adsorbed on Kieselguhr in the presence of oxygen catalyses oxidation of alkyl halides and alkyl tosylates to the aldehydes and ketones in high yields.

One-step conversion of protected alcohols into alkyl halides using dimethylphosgeniminium salt

1997 ◽  
Vol 38 (20) ◽  
pp. 3517-3520 ◽  
Author(s):  
T. Schlama ◽  
V. Gouverneur ◽  
C. Mioskowski
Keyword(s):  
Alkyl Halides ◽  
One Step
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