Stereochemistry of polynuclear compounds of the main group elements. Neutron and x-ray diffraction investigation of lithium-hydrogen-carbon interactions in lithium tetramethylborate

1975 ◽  
Vol 97 (22) ◽  
pp. 6401-6406 ◽  
Author(s):  
Wendell E. Rhine ◽  
Galen Stucky ◽  
S. W. Peterson
Keyword(s):  
Main Group ◽  
X Ray Diffraction ◽  
Main Group Elements ◽  
X Ray ◽  
Polynuclear Compounds

Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen, LXXXIX / Multiple Bonds between Main Group Elements and Transition Metals, LXXXIX

1991 ◽  
Vol 46 (6) ◽  
pp. 747-752 ◽  
Author(s):  
Wolfgang A. Herrmann ◽  
Dieter W. Marz ◽  
Eberhardt Herdtweck
Keyword(s):  
Molecular Structure ◽  
Transition Metals ◽  
Single Crystal ◽  
Main Group ◽  
X Ray Diffraction ◽  
Multiple Bonds ◽  
Main Group Elements ◽  
X Ray ◽  
Clean Synthesis

Reaction of (N-trimethylsilyl)-α-aminopicolin with the rhenium(V) oxohalogenide (η5-C5Me5)ReOCl2 (Me = CH3) exemplifies a simple, clean synthesis of imido-metallosiloxanes, compounds of the structure R3SiO—M=N—R′. The compound (η5-C5Me5)ReCl[OSi(CH3)3](NCH2-2-C5H4N) thus formed under HCl elimination has a square-pyramidal molecular structure (single crystal X-ray diffraction).

Multiple bonds between transition metals and main-group elements. 73. Synthetic routes to rhenium(V) alkyl and rhenium(VII) alkylidyne complexes. X-ray crystal structures of (.eta.5-C5Me5)Re(:O) (CH3)[CH2C(CH3)3] and (.eta.5-C5Me5)(Br)3Re.tplbond.CC(CH3)3

1990 ◽  
Vol 9 (5) ◽  
pp. 1434-1443 ◽  
Author(s):  
Wolfgang A. Herrmann ◽  
Josef K. Felixberger ◽  
Reiner Anwander ◽  
Eberhardt Herdtweck ◽  
Paul Kiprof ◽  
...  
Keyword(s):  
Transition Metals ◽  
Crystal Structures ◽  
Main Group ◽  
Multiple Bonds ◽  
Main Group Elements ◽  
X Ray ◽  
Synthetic Routes
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