Stereochemistry of polynuclear compounds of the main group elements. Bonding and the effect of metal-hydrogen-carbon interactions in the molecular structure of cyclohexyllithium, a hexameric organolithium compound

1974 ◽  
Vol 96 (19) ◽  
pp. 6048-6055 ◽  
Author(s):  
Richard Zerger ◽  
Wendell Rhine ◽  
Galen Stucky
Keyword(s):  
Molecular Structure ◽  
Main Group ◽  
Organolithium Compound ◽  
Main Group Elements ◽  
Polynuclear Compounds

Multiple bonds between Main-Group elements and transition metals. 85. Tetramethyloxoosmium(VI): synthesis, gas-phase molecular structure, photoelectron spectroscopy, and electrochemistry

1991 ◽  
Vol 10 (5) ◽  
pp. 1331-1336 ◽  
Author(s):  
Kristin. Rypdal ◽  
Wolfgang A. Herrmann ◽  
Stefan J. Eder ◽  
Rolf W. Albach ◽  
Petra. Watzlowik ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Transition Metals ◽  
Gas Phase ◽  
Synthesis Gas ◽  
Photoelectron Spectroscopy ◽  
Main Group ◽  
Multiple Bonds ◽  
Main Group Elements

Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen, LXXXIX / Multiple Bonds between Main Group Elements and Transition Metals, LXXXIX

1991 ◽  
Vol 46 (6) ◽  
pp. 747-752 ◽  
Author(s):  
Wolfgang A. Herrmann ◽  
Dieter W. Marz ◽  
Eberhardt Herdtweck
Keyword(s):  
Molecular Structure ◽  
Transition Metals ◽  
Single Crystal ◽  
Main Group ◽  
X Ray Diffraction ◽  
Multiple Bonds ◽  
Main Group Elements ◽  
X Ray ◽  
Clean Synthesis

Reaction of (N-trimethylsilyl)-α-aminopicolin with the rhenium(V) oxohalogenide (η5-C5Me5)ReOCl2 (Me = CH3) exemplifies a simple, clean synthesis of imido-metallosiloxanes, compounds of the structure R3SiO—M=N—R′. The compound (η5-C5Me5)ReCl[OSi(CH3)3](NCH2-2-C5H4N) thus formed under HCl elimination has a square-pyramidal molecular structure (single crystal X-ray diffraction).

Relativistic effects on molecular structure: methyl derivatives of the fourth main-group elements

1986 ◽  
Vol 69 (5-6) ◽  
pp. 437-446 ◽  
Author(s):  
J. Almlof ◽  
K. Faegri
Keyword(s):  
Molecular Structure ◽  
Relativistic Effects ◽  
Main Group ◽  
Main Group Elements ◽  
Methyl Derivatives ◽  
Derivatives Of
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