Identity of Synthetic N6-β-Glyceryllysine and the C14-Labeled Amino Acid Obtained on Sodium Borohydride Reduction and Hydrolysis of a Complex from C14-Fructose 6-Phosphate-Transaldolase Interaction

1963 ◽  
Vol 85 (7) ◽  
pp. 1012-1013 ◽  
Author(s):  
J. C. Speck ◽  
P. T. Rowley ◽  
B. L. Horecker
Keyword(s):  
Amino Acid ◽  
Sodium Borohydride ◽  
Borohydride Reduction ◽  
Sodium Borohydride Reduction ◽  
Hydrolysis Of

scholarly journals Heterocycles. XVII. Sodium borohydride reduction of flavanonols and hydrolysis of (.+-.)-fistacacidin acetates.

1985 ◽  
Vol 33 (8) ◽  
pp. 3134-3141 ◽  
Author(s):  
HIROSHI TAKAHASHI ◽  
YUMIKO KUBOTA ◽  
MIEKO IGUCHI ◽  
MASAYUKI ONDA
Keyword(s):  
Sodium Borohydride ◽  
Borohydride Reduction ◽  
Sodium Borohydride Reduction ◽  
Hydrolysis Of

The structure and function of oestrogens. V. Synthesis of (9,12,12-2H3)- and (11ζ 12,12-2H3)-oestradiol

1983 ◽  
Vol 36 (2) ◽  
pp. 403 ◽  
Author(s):  
DJ Collins
Keyword(s):  
Acid Hydrolysis ◽  
Sodium Borohydride ◽  
Structure And Function ◽  
Borohydride Reduction ◽  
Hydride Reduction ◽  
Biological Studies ◽  
Sodium Borohydride Reduction ◽  
And Function ◽  
Hydrolysis Of

17,17-Ethylenedioxy-3-methoxy(9,12,12-2H3)-9β-oestra-l,3,5(10)-trien-11-one (3) was reduced to the mixture of 11-epimeric alcohols (4) which upon elimination of DHO gave the (12,12-2H2)-9(11)- dehydrooestrone derivative (5b). Treatment of (5b) with (2H6)diborane followed by oxidation afforded the (9,12,12-2H3)alcohol (8a); hydride reduction of the corresponding tosylate then gave 17,17-ethylenedioxy-3-methoxy(9,12,12-2H3)oestra-l,3,5(l0)-triene (7). Acid hydrolysis of (7), followed by demethylation, and reduction with sodium borohydride yielded (9,12,12-2H3)oestradiol (10). Sodium borohydride reduction of (11&12,12-2H3)oestrone (6),prepared in several steps from the 9β,12,12-trideutero ketone (3), gave (11 ξ,12,12-2H3)oestradiol (9). [The two trideuterated oestradiols (9) and (10) were required for biological studies.]

scholarly journals FACILE PREPARATION OF PLATINUM SOLS BY SODIUM BOROHYDRIDE REDUCTION AND ITS EVALUATION IN THE PHOTOSENSITIZED REDUCTION OF WATER TO HYDROGEN

1983 ◽  
Vol 12 (6) ◽  
pp. 893-896 ◽  
Author(s):  
Yohmei Okuno ◽  
Yukihiro Chiba ◽  
Osamu Yonemitsu
Keyword(s):  
Sodium Borohydride ◽  
Borohydride Reduction ◽  
Sodium Borohydride Reduction ◽  
Facile Preparation

1,2-Benzothiazines. II. The Preparation and Sodium Borohydride Reduction of 3-Acyl-2H-1,2-benzothiazin-4(3H)-one 1,1-Dioxides1

1965 ◽  
Vol 30 (7) ◽  
pp. 2241-2246 ◽  
Author(s):  
Harold Zinnes ◽  
Roger A. Comes ◽  
Francis R. Zuleski ◽  
Albert N. Caro ◽  
John Shavel
Keyword(s):  
Sodium Borohydride ◽  
Borohydride Reduction ◽  
Sodium Borohydride Reduction
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