THE IONIC ACTIVITY COEFFICIENT PRODUCT AND DISSOCIATION OF WATER IN BARIUM CHLORIDE SOLUTIONS AT 25°

1932 ◽  
Vol 54 (8) ◽  
pp. 3112-3120 ◽  
Author(s):  
Herbert S. Harned ◽  
C. Morgan Mason
Keyword(s):  
Activity Coefficient ◽  
Barium Chloride ◽  
Chloride Solutions ◽  
Ionic Activity

The Ionic Activity Coefficient Product and Ionization of Water in Barium Chloride Solutions from 0 to 50°

1937 ◽  
Vol 59 (10) ◽  
pp. 2032-2035 ◽  
Author(s):  
Herbert S. Harned ◽  
Charles G. Geary
Keyword(s):  
Activity Coefficient ◽  
Barium Chloride ◽  
Chloride Solutions ◽  
Ionic Activity ◽  
Ionization Of Water

Activity coefficient assumptions m the determination of the association constant of thallons chloride. II. Effect of interactions between freeions

1966 ◽  
Vol 19 (6) ◽  
pp. 915 ◽  
Author(s):  
JB Macaskill ◽  
MH Panckhurst
Keyword(s):  
Sodium Chloride ◽  
Activity Coefficient ◽  
Association Constant ◽  
Sodium Perchlorate ◽  
Barium Chloride ◽  
Specific Interactions ◽  
Ionic Activity ◽  
Caesium Chloride ◽  
Free Ions

The solubility of thallous chloride has been measured in solutions of hydrochloric acid, caesium chloride, caesium perchlorate, barium chloride, and in various mixtures of sodium chloride and sodium perchlorate. These measurements are analysed to give the association constant for thallous chloride, paying particular attention to ionic activity coefficient formulae. It is shown that an activity coefficient expression which assumes no specific interactions between free ions is unsatisfactory in contrast to an expression which assumes such interactions. The consequences of this are discussed.

THE ACTIVITY COEFFICIENT OF HYDROCHLORIC ACID IN ALUMINUM CHLORIDE SOLUTIONS

1931 ◽  
Vol 53 (9) ◽  
pp. 3377-3380 ◽  
Author(s):  
Herbert S. Harned ◽  
C. Morgan. Mason
Keyword(s):  
Hydrochloric Acid ◽  
Activity Coefficient ◽  
Aluminum Chloride ◽  
Chloride Solutions

Mixture Property: Mean Ionic Activity and Mean Ionic Activity Coefficient

2016 ◽  
Author(s):  
Michael Frenkel ◽  
Robert D. Chirico ◽  
Vladimir Diky ◽  
Paul L. Brown ◽  
John H. Dymond ◽  
...  
Keyword(s):  
Activity Coefficient ◽  
Ionic Activity

Mean ionic activity coefficient ratio of NaBr and DL-valine in the (water+DL-valine+NaBr+K3PO4) system at T=(298.2 and 303.2)K

2014 ◽  
Vol 68 ◽  
pp. 25-31 ◽  
Author(s):  
Sepideh Amjad-Iranagh ◽  
Mahdi Zaeifi Yamchi ◽  
Majid Abdouss ◽  
Hamid Modarress
Keyword(s):  
Activity Coefficient ◽  
Ionic Activity ◽  
Activity Coefficient Ratio

scholarly journals The ionic activity function of water and the activity coefficient of the hydrogen ion in seawater

1973 ◽  
Vol 18 (5) ◽  
pp. 784-787 ◽  
Author(s):  
J. V. LEYENDEKKERS
Keyword(s):  
Activity Coefficient ◽  
Hydrogen Ion ◽  
Ionic Activity

Dissociation Degree of HSO-4 and Mean Ionic Activity Coefficient of Aqueous Sulfuric Acid of Different Molalities up to 473 K and 975 bar

1994 ◽  
Vol 49 (10) ◽  
pp. 939-942
Author(s):  
B. A. Bilal ◽  
E. Müller
Keyword(s):  
Sulfuric Acid ◽  
Activity Coefficient ◽  
Thermodynamic Data ◽  
Formation Constant ◽  
Saturation Pressure ◽  
Ionic Activity ◽  
The Real ◽  
Aqueous Sulfuric Acid ◽  
Dissociation Degree

AbstractThe apparent formation constant and the dissociation degree of HSO-4 in aqueous H2SO4 of the molalities 0.1, 0.5, and 1.0 m, as well as the real mean ionic coefficient have been calculated up to 473 K and 975 bar using the thermodynamic data reported by Holmes and Mesmer at saturation pressure and those given by the authors at higher pressure.

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