Nitromethane: The Vapor Heat Capacity, Heat of Vaporization, Vapor Pressure and Gas Imperfection; the Chemical Thermodynamic Properties from 0 to 1500°K.

1954 ◽  
Vol 76 (19) ◽  
pp. 4791-4796 ◽  
Author(s):  
J. P. McCullough ◽  
D. W. Scott ◽  
R. E. Pennington ◽  
I. A. Hossenlopp ◽  
Guy Waddington



Author(s):  
Janiel J. Reed

The NBS Tables of Chemical Thermodynamic Properties is a collection of thermodynamic properties, published in book form, consisting of 103 tables with 14 330 critically evaluated species. The tables were originally published as a series of NBS Technical Notes As a result of this work, the data is now available in a more accessible spreadsheet format. Enthalpy of formation, ΔfH°, Gibbs energy of formation, ΔfG°, entropy, S°, heat capacity at constant pressure, Cp°, all at 298.15 K, and the enthalpy difference, [H°(298) – H°(0)] are provided where known. Within this collection of data, there are no values given for transuranic elements, Np to Lr (Tables 77–87).



1986 ◽  
Vol 64 (4) ◽  
pp. 635-640 ◽  
Author(s):  
J. Peter Guthrie

At any pressure the heat of vaporization can be expressed as a quadratic function of the boiling point at that pressure. A seven parameter equation expressing the simultaneous dependence on boiling point and pressure can be fitted to the data; six pressures from 1 to 760 Torr (1 Torr = 133.3 Pa) were used. ΔHvap = b11 + b12 In (p) + b13p + (b21 + b22 In (p))tbp + (b31 + b32 In (p))tbp2. This relationship served as a guide for developing a relationship between vapour pressure at 25 °C and the calorimetric heat of vaporization, and also a relationship between vapor pressure at 25 °C and the boiling point at some other pressure. Parameters for both these relationships could be derived from the parameters obtained for ΔHvap as a function of temperature and pressure. A third method was developed starting from an equation for vapor pressure and fitting to the heat of vaporization, the heat capacity of vaporization, and at least one t,p point. These methods allow the estimation of the vapor pressure at room temperature from very meager data. The problems of errors in estimated values are discussed.





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