ELECTROMOTIVE-FORCE MEASUREMENTS WITH A SATURATED POTASSIUM CHLORIDE BRIDGE OR WITH CONCENTRATION CELLS WITH A LIQUID JUNCTION

1923 ◽  
Vol 45 (7) ◽  
pp. 1716-1723 ◽  
Author(s):  
George Scatchard
Keyword(s):  
Potassium Chloride ◽  
Electromotive Force ◽  
Force Measurements ◽  
Liquid Junction ◽  
Electromotive Force Measurements ◽  
Concentration Cells

scholarly journals THE COMBINATION OF EDESTIN WITH HYDROCHLORIC ACID

1930 ◽  
Vol 14 (1) ◽  
pp. 99-103 ◽  
Author(s):  
David I. Hitchcock
Keyword(s):  
Hydrochloric Acid ◽  
Electromotive Force ◽  
Force Measurements ◽  
Liquid Junction ◽  
Electromotive Force Measurements

Electromotive force measurements of cells without liquid junction, of the type Ag, AgCl, HCl + protein, H2, lead to the conclusion that 1 gm. of edestin (or, more probably, edestan) combines with a maximum of 13.4 x 10–4 equivalents of H+ and 3.9 x 10–4 equivalents of Cl-, when the protein is dissolved in 0.1 M HCl.

Potentiométrie de précision à basse température dans les mélanges eau – éthylène glycol; grandeurs thermodynamiques relatives aux ionisations de l'acide acétique et du solvant mixte

1983 ◽  
Vol 61 (10) ◽  
pp. 2344-2348 ◽  
Author(s):  
Hamed Bahri ◽  
Jean-Claude Hallé ◽  
Robert Schaal
Keyword(s):  
Ethylene Glycol ◽  
Electromotive Force ◽  
Dissociation Constants ◽  
Silver Chloride ◽  
Force Measurements ◽  
Liquid Junction ◽  
Solvent Water ◽  
Electromotive Force Measurements ◽  
Silver Silver ◽  
Silver Silver Chloride

Electromotive force measurements of cells without liquid-junction containing hydrogen electrodes and silver – silver chloride electrodes have been used to derive the dissociation constants of acetic acid and solvent water – ethylene glycol mixtures (50 and 70 mass % of ethyleneglycol) at 14 temperatures from −35 to 30 °C. Primary acidity standards related to these acetic buffered and sodium hydroxide solutions are given.

Thermodynamic properties of the Na–Bi–Pb system

1994 ◽  
Vol 72 (2) ◽  
pp. 369-371 ◽  
Author(s):  
Peter J. Tumidajski
Keyword(s):  
Thermodynamic Properties ◽  
Electromotive Force ◽  
Coulometric Titration ◽  
Ionic Character ◽  
Force Measurements ◽  
Complex Species ◽  
Species Formation ◽  
Electromotive Force Measurements ◽  
Concentration Cells ◽  
Titration Technique

Thermodynamic properties of Na in an equimolar Bi–Pb alloy were determined at 723 K for compositions of 0.0075 ≤ XNa ≤ 0.1000 from electromotive force measurements on Na metal concentration cells with a solid Na–β-Al2O3 electrolyte. A coulometric titration technique was used to electrochemically generate the Na metal in the Bi–Pb alloy. The results indicate that, as Na is added to Bi–Pb, the liquid becomes more associated and suggests complex species formation with an ionic character intermediate between those observed for the constituent binaries.

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