Potentiométrie de précision à basse température dans les mélanges eau – éthylène glycol; grandeurs thermodynamiques relatives aux ionisations de l'acide acétique et du solvant mixte

1983 ◽  
Vol 61 (10) ◽  
pp. 2344-2348 ◽  
Author(s):  
Hamed Bahri ◽  
Jean-Claude Hallé ◽  
Robert Schaal
Keyword(s):  
Ethylene Glycol ◽  
Electromotive Force ◽  
Dissociation Constants ◽  
Silver Chloride ◽  
Force Measurements ◽  
Liquid Junction ◽  
Solvent Water ◽  
Electromotive Force Measurements ◽  
Silver Silver ◽  
Silver Silver Chloride

Electromotive force measurements of cells without liquid-junction containing hydrogen electrodes and silver – silver chloride electrodes have been used to derive the dissociation constants of acetic acid and solvent water – ethylene glycol mixtures (50 and 70 mass % of ethyleneglycol) at 14 temperatures from −35 to 30 °C. Primary acidity standards related to these acetic buffered and sodium hydroxide solutions are given.

scholarly journals Determination of Dissociation Constants of Malonic Acid in (Ethylene Glycol-Water)X% Mixed Solvent at Different Temperatures Using Electromotive Force Measurements

2019 ◽  
Vol 7 (1) ◽  
pp. 18-26
Author(s):  
Soleen S. Ahmed ◽  
Lazgin A. Jamil
Keyword(s):  
Ethylene Glycol ◽  
Malonic Acid ◽  
Electromotive Force ◽  
Mixed Solvent ◽  
Dissociation Constants ◽  
Standard Entropy ◽  
Thermodynamic Quantities ◽  
Force Measurements ◽  
Electromotive Force Measurements ◽  
Different Temperatures

The first and second dissociation constants of malonic acid in different composition of (ethylene glycol-water)%, (10, 20 and 30)% mixed solvent determined using the electromotive force measurements of galvanic cells without liquid junction at nine different temperatures,  at  interval, including the body temperature. The value of the first and second thermodynamic dissociation constants have been used to determine the thermodynamic quantities of two dissociation processes. These quantities involved the standard free energy,  standard enthalpy change,  standard entropy change,  and standard heat capacity change.

Thermodynamics of ionization of trans-crotonic and adipic acids in water; the silver – silver adipate electrode

1980 ◽  
Vol 58 (4) ◽  
pp. 323-327 ◽  
Author(s):  
Upendra Nath Dash ◽  
Uttam Kumar Nayak
Keyword(s):  
Adipic Acid ◽  
Silver Chloride ◽  
Ionization Constants ◽  
Thermodynamic Quantities ◽  
Liquid Junction ◽  
Different Temperatures ◽  
Heat Capacity Changes ◽  
Silver Silver ◽  
Silver Silver Chloride ◽  
Thermodynamics Of Ionization

The ionization constant, K, of trans-crotonic acid, and the first and second ionization constants, K1 and K2, of adipic acid have been determined in water at seven different temperatures ranging from 15 to 45 °C with the help of the cells without liquid junction using silver – silver chloride and quinhydrone electrodes. The variations of pK, pK1, and pK2 with temperature have been expressed by the equations[Formula: see text]and[Formula: see text]From the temperature coefficient of the ionization constants, the standard enthalpy, entropy, Gibbs energy, and heat capacity changes of the corresponding dissociation processes have been calculated. Using the values of ionization constants of adipic acid, the standard potential of the Ag(s)/Ag2Ad(s)/Ad2− electrode, and the related standard thermodynamic quantities for the electrode process[Formula: see text]have been calculated in water at those temperatures.

scholarly journals Studies on the application of the quinhydrone electrode in formamide. III. The ionization constants and related thermodynamic quantities of phthalic acid frome.m.f. measurements at different temperatures

1975 ◽  
Vol 28 (4) ◽  
pp. 793 ◽  
Author(s):  
UN Dash ◽  
B Nayak
Keyword(s):  
Phthalic Acid ◽  
Silver Chloride ◽  
Ionization Constants ◽  
Thermodynamic Quantities ◽  
Liquid Junction ◽  
Different Temperatures ◽  
Silver Silver ◽  
Silver Silver Chloride

The first and second ionization constants of phthalic acid have been determined, in formamide, at temperatures ranging from 5� to 45�C at 5� intervals, with the help of cells without liquid junction using quinhydrone and silver-silver chloride electrodes. By means of the Bjerrum equation, the distance r between the acidic groups has been estimated in formamide at different temperatures.

Studies on the application of the quinhydrone electrode in formamide. II. The ionization constants of phthalic acid from E.M.F. measurements at 25°

1973 ◽  
Vol 26 (1) ◽  
pp. 115 ◽  
Author(s):  
B Nayak ◽  
UN Dash
Keyword(s):  
Phthalic Acid ◽  
Silver Chloride ◽  
Ionization Constants ◽  
Liquid Junction ◽  
Silver Silver ◽  
Silver Silver Chloride

The first and the second ionization constants of phthalic acid have been determined, in formamide, at 25� with the help of cells without liquid junction using quinhydrone and silver-silver chloride electrodes. The values of pK1a and pK2a were found to be 4.214�0.02 and 7.716�0.01, respectively, at this temperature.

scholarly journals THE COMBINATION OF EDESTIN WITH HYDROCHLORIC ACID

1930 ◽  
Vol 14 (1) ◽  
pp. 99-103 ◽  
Author(s):  
David I. Hitchcock
Keyword(s):  
Hydrochloric Acid ◽  
Electromotive Force ◽  
Force Measurements ◽  
Liquid Junction ◽  
Electromotive Force Measurements

Electromotive force measurements of cells without liquid junction, of the type Ag, AgCl, HCl + protein, H2, lead to the conclusion that 1 gm. of edestin (or, more probably, edestan) combines with a maximum of 13.4 x 10–4 equivalents of H+ and 3.9 x 10–4 equivalents of Cl-, when the protein is dissolved in 0.1 M HCl.

VOLTAIC CELLS IN FUSED SALTS: PART II. THE SYSTEMS: (a) SILVER – SILVER CHLORIDE, LEAD – LEAD CHLORIDE; (b) SILVER – SILVER CHLORIDE, ZINC – ZINC CHLORIDE; AND (c) SILVER – SILVER CHLORIDE, NICKEL – NICKELOUS CHLORIDE

1957 ◽  
Vol 35 (11) ◽  
pp. 1254-1259 ◽  
Author(s):  
S. N. Flengas ◽  
T. R. Ingraham
Keyword(s):  
Zinc Chloride ◽  
Dissociation Constants ◽  
Silver Chloride ◽  
Reference Electrode ◽  
Lead Chloride ◽  
Effect Of Temperature ◽  
Fused Salts ◽  
Electrode Potentials ◽  
Silver Silver ◽  
Silver Silver Chloride

Using a reversible silver – silver chloride reference electrode, described in the first paper of this series, standard electrode potentials have been established for the systems lead – lead chloride, zinc – zinc chloride, and nickel – nickelous chloride, in melts containing equimolar quantities of KCl and NaCl. Deviations from ideality were observed, and these were attributed to the formation of complexes. Dissociation constants for the complexes were calculated. The effect of temperature on the electromotive forces of the voltaic cells was also measured, and the heats of the cell reactions were calculated from the data.

VOLTAIC CELLS IN FUSED SALTS: PART I. THE SILVER – SILVER CHLORIDE, COBALT – COBALTOUS CHLORIDE SYSTEM

1957 ◽  
Vol 35 (10) ◽  
pp. 1139-1149 ◽  
Author(s):  
S. N. Flengas ◽  
T. R. Ingraham
Keyword(s):  
Electromotive Force ◽  
Silver Chloride ◽  
Reference Electrode ◽  
Effect Of Temperature ◽  
Chloride System ◽  
Fused Salts ◽  
Silver Silver ◽  
The Right ◽  
Silver Silver Chloride ◽  
Voltaic Cell

A reversible silver − silver chloride reference electrode for use in melts at high temperatures has been developed. It was found that the solution of silver chloride in an equimolar mixture of KCl–NaCl melt is ideal for the range of concentrations studied, i.e. 1.0 × 10−3 to 6.0 × 10−2 mole fraction of AgCl.The electromotive force of the voltaic cell[Formula: see text]in which the half-cell to the right contains the above-mentioned reference electrode, was measured as a function of CoCl2 concentration. The applicability of the Nernst equation to this system was established. Deviation from ideality was observed in the case of the solution of CoCl2 in the melt solvent, and this was attributed to the formation of a complex. The dissociation constant of this complex was calculated as 4.50 × 10−2 at 710 °C.The effect of temperature on the electromotive force of this cell was also measured, and the heat of the cell reaction in the presence of solvent (Co + 2AgCl → CoCl2 + 2Ag) was calculated from the data as 22.8 ± 1.3 kcal.The thermodynamic significance of the standard electrode potential of the Co–Ag voltaic cell, derived experimentally as 0.324 volt, is discussed briefly.

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