Thiolate-Bridged Nickel−Copper Complexes:  A Binuclear Model for the Catalytic Site of Acetyl Coenzyme A Synthase?

2003 ◽  
Vol 125 (15) ◽  
pp. 4422-4423 ◽  
Author(s):  
Rangan Krishnan ◽  
Janis K. Voo ◽  
Charles G. Riordan ◽  
Lev Zahkarov ◽  
Arnold L. Rheingold
Keyword(s):  
Copper Complexes ◽  
Coenzyme A ◽  
Catalytic Site ◽  
Acetyl Coenzyme A ◽  
Acetyl Coenzyme ◽  
Nickel Copper ◽  
Acetyl Coenzyme A Synthase

Methyl Transfer from Methylcobaloxime to (Triphos)Ni(PPh3):  Relevance to the Mechanism of Acetyl Coenzyme A Synthase

2007 ◽  
Vol 129 (30) ◽  
pp. 9286-9287 ◽  
Author(s):  
Nathan A. Eckert ◽  
William G. Dougherty ◽  
Glenn P. A. Yap ◽  
Charles G. Riordan
Keyword(s):  
Coenzyme A ◽  
Acetyl Coenzyme A ◽  
Acetyl Coenzyme ◽  
Methyl Transfer ◽  
Acetyl Coenzyme A Synthase

scholarly journals Bisamidate and Mixed Amine/Amidate NiN2S2Complexes as Models for Nickel-Containing Acetyl Coenzyme A Synthase and Superoxide Dismutase: An Experimental and Computational Study

2010 ◽  
Vol 49 (12) ◽  
pp. 5393-5406 ◽  
Author(s):  
Vaidyanathan Mathrubootham ◽  
Jason Thomas ◽  
Richard Staples ◽  
John McCraken ◽  
Jason Shearer ◽  
...  
Keyword(s):  
Superoxide Dismutase ◽  
Coenzyme A ◽  
Computational Study ◽  
Acetyl Coenzyme A ◽  
Acetyl Coenzyme ◽  
Acetyl Coenzyme A Synthase

Reaction of a polydentate cysteine-based ligand and its nickel(ii) complex with electrophilic and nucleophilic methyl-transfer reagents – from S-methylation to acetyl coenzyme A synthase reactivity

2015 ◽  
Vol 44 (42) ◽  
pp. 18378-18385 ◽  
Author(s):  
D. S. Warner ◽  
C. Limberg ◽  
F. J. Oldenburg ◽  
B. Braun
Keyword(s):  
Coenzyme A ◽  
Acetyl Coenzyme A ◽  
Acetyl Coenzyme ◽  
Methyl Transfer ◽  
Acetyl Coenzyme A Synthase

A cysteine-based nickel(ii) complex reacts with methylating reagents followed by CO treatment via acetylation of the thiolate function corresponding to the ACS reactivity.

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