Metal-Ion Sensing Fluorophores with Large Two-Photon Absorption Cross Sections:  Aza-Crown Ether Substituted Donor−Acceptor−Donor Distyrylbenzenes

2004 ◽  
Vol 126 (30) ◽  
pp. 9291-9306 ◽  
Author(s):  
Stephanie J. K. Pond ◽  
Osamu Tsutsumi ◽  
Mariacristina Rumi ◽  
Ohyun Kwon ◽  
Egbert Zojer ◽  
...  
2007 ◽  
Vol 111 (28) ◽  
pp. 10673-10681 ◽  
Author(s):  
Fei Huang ◽  
Yanqing Tian ◽  
Ching-Yi Chen ◽  
Yen-Ju Cheng ◽  
A. Cody Young ◽  
...  

2015 ◽  
Vol 3 (4) ◽  
pp. 742-749 ◽  
Author(s):  
Anna Purc ◽  
Krzysztof Sobczyk ◽  
Yusuke Sakagami ◽  
Akihiro Ando ◽  
Kenji Kamada ◽  
...  

Decorating diketopyrrolopyrroles with strongly electron-rich heterocycles led to donor–acceptor–donor architectures possessing two-photon brightness 850–1900 GM.


2010 ◽  
Vol 114 (28) ◽  
pp. 9313-9321 ◽  
Author(s):  
Kevin D. Belfield ◽  
Mykhailo V. Bondar ◽  
Andrew Frazer ◽  
Alma R. Morales ◽  
Oleksiy D. Kachkovsky ◽  
...  

2006 ◽  
Vol 937 ◽  
Author(s):  
Heiner Detert ◽  
Volker Schmitt ◽  
Stefan Glang

ABSTRACT1,4-Distyrylbenzenes with terminal dialkylamino groups and a central 2,5-disubstitution with electron-accepting groups were prepared via twofold Horner-olefination. These chromophores with a quadrupolar donor-acceptor-donor substitution and C2-symmetry absorb in the violet to green region of the visible spectrum exhibit large two-photon-absorption cross-sections when irrdiated in the NIR. Whereas a variation of the solvent polarity only slightly alters the absorption spectra, the fluorescence appears to be highly responsive. Besides a positive solvatochromism, the emission is very sensitive towards protonation. Quenching or appearance of new emitting species depends on the substitution pattern and is controlled by the concentration of the acid.


ChemInform ◽  
2006 ◽  
Vol 37 (52) ◽  
Author(s):  
Jong Seung Kim ◽  
Hyun Jung Kim ◽  
Hwan Myung Kim ◽  
Su Ho Kim ◽  
Jeong Won Lee ◽  
...  

2019 ◽  
Vol 955 ◽  
pp. 37-43
Author(s):  
Martin Vala ◽  
Matouš Kratochvíl ◽  
Patricie Heinrichova ◽  
Martin Weiter

The paper deals with determination of two-photon absorption cross-sections of selected representatives of diketo-pyrrolo-pyrrole. The materials were optimized in order to test the influence of various substitutions on the diketo-pyrrolo-pyrrole basic molecule. The two-photon absorption cross-sections were determined using two-photon excited fluorescence technique. A considerably high two-photon absorption cross-section in order of 1000 GM was found for non-symmetrically substituted derivative with donor-acceptor structure. All of the derivatives showed strong fluorescence in solid state visible by naked eye. These results demonstrate that this class of materials can be used in e.g. two-photon fluorescence microscopy in the form of nanoparticles.


2006 ◽  
Vol 71 (21) ◽  
pp. 8016-8022 ◽  
Author(s):  
Jong Seung Kim ◽  
Hyun Jung Kim ◽  
Hwan Myung Kim ◽  
Su Ho Kim ◽  
Jeong Won Lee ◽  
...  

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