Chiral Recognition in the Gas Phase Chiral Recognition in the Gas Phase . Edited by Anne Zehnacker (French Center for Scientific Research, Orsay, France). CRC Press (an imprint of Taylor & Francis Group): Boca Raton, FL. 2010. xviii + 226 pp. $99.95. ISBN 978-1-4200-8227-2 .

2010 ◽  
Vol 132 (43) ◽  
pp. 15457-15457
Author(s):  
W. Andy Tao
Keyword(s):  
Gas Phase ◽  
Chiral Recognition ◽  
Scientific Research

scholarly journals Enantioselective supramolecular devices in the gas phase. Resorcin[4]arene as a model system

2012 ◽  
Vol 8 ◽  
pp. 539-550 ◽  
Author(s):  
Caterina Fraschetti ◽  
Matthias C Letzel ◽  
Antonello Filippi ◽  
Maurizio Speranza ◽  
Jochen Mattay
Keyword(s):  
Gas Phase ◽  
Chiral Recognition ◽  
Experimental Approach ◽  
Biologically Active ◽  
Computational Techniques ◽  
Ligand Displacement ◽  
Artificial Receptor ◽  
Ion Molecule Complexes ◽  
Supramolecular Devices ◽  
Diastereomeric Complexes

This review describes the state-of-art in the field of the gas-phase reactivity of diastereomeric complexes formed between a chiral artificial receptor and a biologically active molecule. The presented experimental approach is a ligand-displacement reaction carried out in a nano ESI-FT-ICR instrument, supported by a thermodynamic MS-study and molecular-mechanics and molecular-dynamics (MM/MD) computational techniques. The noncovalent ion–molecule complexes are ideal for the study of chiral recognition in the absence of complicating solvent and counterion effects.

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